32993-05-8Relevant articles and documents
A VERSATILE ROUTE TO (η5-C5R5)RuL2X FROM ALLYLMETHYLRUTHENIUM COMPLEXES
Nagashima, Hideo,Yamaguchi, Keitaro,Mukai, Katsunori,Itoh, Kenji
, p. C20 - C22 (1985)
Divalent ruthenium complexes, (η5-C5R5)RuL2X (R=H, CH3; X=Br, Cl), are formed by thermal decomposition of (η5-C5R5)Ru(CH3)X(η3-C3H5) in the presence of several neutral ligands.
A new ruthenium cyclopentadienyl azole compound with activity on tumor cell lines and trypanosomatid parasites
Rodríguez Arce, Esteban,Sarniguet, Cynthia,Moraes, Tania S.,Vieites, Marisol,Tomaz, A. Isabel,Medeiros, Andrea,Comini, Marcelo A.,Varela, Javier,Cerecetto, Hugo,González, Mercedes,Marques, Fernanda,García, M. Helena,Otero, Lucía,Gambino, Dinorah
, p. 2923 - 2937 (2015)
(Chemical Equation Presented). As part of our efforts to develop organometallic ruthenium compounds bearing activity on both trypanosomatid parasites and tumor cells, a new Ru(II)-cyclopentadienyl clotrimazole complex, [RuCp(PPh3)2(C
The Kinatics of the Reaction of with Various Olefins
Alibrandi, Giuseppe,Mann, Brian E.
, p. 951 - 954 (1994)
A detailed kinetic investigation of the reaction of with cycloheptatriene, cyclohepta-1,3-diene, cyclooctatetraene, penta-1,4-diene, cycloocta-1,5-diene and dimethyl maleate, has been carried out spectrophotometrically in CH2Cl2 at 10 deg C.It is shown that the major mechanism is via dissociation of PPh3 to give which then reacts with the olefin.There is also a second mechanism involving direct attack of the olefin on .
Ashok, R. F. N.,Gupta, M.,Arulsamy, K. S.,Agarwala, U. C.
, p. 169 - 180 (1985)
Solvent- A nd anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes
Hall, Lewis M.,Milner, Lucy M.,Hart, Sam J.,Whitwood, Adrian C.,Lynam, Jason M.,Slattery, John M.
supporting information, p. 17655 - 17659 (2019/12/23)
The construction of fluorocarbene ligands within the coordination sphere of transition metal complexes using sequential nucleophilic and electrophilic addition to a vinylidene complex is described. Reaction of [Ru(η5-C5H5)(dppe)(CCPhF)][N(SO2Ph)2] with [NMe4]F results in nucleophilic attack of fluoride at the metal-bound carbon of the vinylidene ligand to give alkenyl complex [Ru(η5-C5H5)(dppe)(-CFCFPh)]. Subsequent eletrophilic fluorination with N-fluorobenzenesulfonimide (NFSI) results in the formation of the fluorinated carbene complex [Ru(η5-C5H5)(dppe)(CF-CHFPh)][N(SO2Ph)2]. The fluorocarbene complexes undergo rearrangement to liberate free fluorinated alkenes, a process governed by the choice of solvent and anion, representing a new metal-mediated route to fluorinated alkenes from alkynes.
Syntheses of transition metal methoxysiloxides
Richers, Casseday P.,Bertke, Jeffery A.,Rauchfuss, Thomas B.
supporting information, p. 8756 - 8762 (2017/07/22)
The paper describes three methods for the preparation of methoxysiloxide complexes, a rare class of complexes of relevance to room temperature vulcanization (RTV) of polysiloxanes. The salt metathesis reaction involves the use of the recently described re
