33023-02-8

Basic information

• Product Name: Elaeokanine B
• Synonyms: (-)-Eleokanin B;(αS,8aS)-1,2,3,5,6,8a-Hexahydro-α-propyl-8-indolizinemethanol;[8aS,αS,(-)]-1,2,3,5,6,8a-Hexahydro-α-propyl-8-indolizinemethanol;Elaeokanine B
• CAS NO: 33023-02-8
• Molecular Formula: C12H21NO
• Molecular Weight: 195.30124
• Mol File: 33023-02-8.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Elaeokanine B(CAS DataBase Reference)
• NIST Chemistry Reference: Elaeokanine B(33023-02-8)
• EPA Substance Registry System: Elaeokanine B(33023-02-8)

Safety Data

• Hazardous Substances Data: 33023-02-8(Hazardous Substances Data)

Upstream product

• 927-77-5 n-propylmagnesium bromide 
• 76307-12-5 1,2,3,5,6,8a-Hexahydro-indolizine-8-carbaldehyde 
• 73971-35-4 1,5,6,8a-tetrahydro-8-(1-hydroxybutyl)-3(2H)-indolizinone 
• 123-72-8 butyraldehyde 
• 109720-83-4 8-bromo-1,2,3,5,6,8a-hexahydroindolizine 
• 87682-76-6 8-bromo-1,5,6,8a-tetrahydro-3-(2H)-indolizinone 
• 87682-74-4 N-<(E)-4-(trimethylsilyl)-4-bromo-3-butenyl>succinimide 
• 109720-82-3 N-<(E)-4-(trimethylsilyl)-3-bromo-3-butenyl>-5-hydroxypyrrolid-2one 
• 73971-24-1 1-<2-(3-butenyl)-2,5-dihydro-3-thienyl>-1-butanone 
• 79476-93-0 dimethyl <1-(1-oxobutyl)-1,5-hexadienyl>phosphonate 
• 73971-25-2 1-<2,5-dihydro-2-(2-oxiranylethyl)-3-thienyl>-1-butanone S,S-dioxide 
• 411220-33-2 8-(1-Trimethylsilanyloxy-butyl)-1,5,6,8a-tetrahydro-2H-indolizin-3-one 
• 73971-26-3 2,5-dihydro-3-(1-oxobutyl)-2-thiophenepropanoic acid 1,1-dioxide 
• 73971-27-4 2,5-dihydro-3-(1-oxobutyl)-2-thiophenepropanamide 1,1-dioxide 

Relevant articles and documents

Total Sythesis of Elaeokanine A

A new general approach to synthesis of Elaeocarpus alkaloids is described which utilizes the intramolecular imino Diels-Alder reaction as the key ring-forming step.The methodology has been applied to total synthesis of the alkaloid Elaeokanine A.

A Practical Preparation of the Indolizidine Nucleus: Synthesis of (+/-)-Elaeokanine A

Reduction of 3 followed by acid-catalyzed cyclization provides α,β-unsaturated ester 5.As 3 can be prepared in two steps from succinimide, acrolein, and trimethyl phosphonoacetate, this is a practical method for the assembly of the indolizidine nucleus.The structure of 5 was secured by conversion to elaeokanine A, 7.

Iminium Ion and Acyliminium Ion Initiated Cyclizations of Vinylsilanes. Regiocontrolled Construction of Unsaturated Azacyclics

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