33027-66-6Relevant articles and documents
Preparation method of pentafluoroethoxycyclotriphosphazene
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Paragraph 0033-0037, (2019/03/28)
The invention discloses a preparation method of pentafluoroethoxycyclotriphosphazene. The preparation method comprises the following steps: (1) adding reactants including hexafluorocyclotriphosphazeneand ethanol to an organic solvent, and adding a catalyst and an acid binding agent so as to obtain a reaction liquid after completion of a reaction; and (2) filtering the reaction liquid so as to obtain a filtrate, and rectifying the filtrate so as to obtain the target product pentafluoroethoxycyclotriphosphazene, wherein the organic solvent is an arbitrary one of n-hexane, cyclohexane, toluene,xylene, chlorobenzene, acetonitrile, acetone, tetrahydrofuran, dioxane, petroleum ether, ethyl acetate, dichloroethane, dimethyl carbonate and diethyl carbonate, and the catalyst comprises a main catalyst and a cocatalyst; and the main catalyst is alkali metal iodide, the cocatalyst is a phase transfer catalyst, and the acid binding agent is an arbitrary one of sodium carbonate, potassium carbonate, ammonia and triethylamine. The preparation method of pentafluoroethoxycyclotriphosphazene has a low reaction temperature, few by-products and a high conversion rate.
Preparation method of pentafluoroalkoxyl cyclotriphosphazene
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Paragraph 0016-0031, (2018/03/24)
The invention discloses a preparation method of pentafluoroalkoxyl cyclotriphosphazene. The preparation method comprises the following steps: (1) adding hexachlorocyclotriphosphazene, a fluorinating agent and an organic solvent into a reaction container for reaction at a temperature between -30 DEG C and 80 DEG C to obtain a reaction solution containing hexafluorocyclotriphosphazene; (2) washing the reaction solution obtained in the step (1) with water, then carrying out standing for liquid separation to obtain an organic phase containing hexafluorocyclotriphosphazene, and distilling the organic phase to obtain the hexafluorocyclotriphosphazene; (3) adding an organic solvent, an alcohol, an acid binding agent and the hexafluorocyclotriphosphazene obtained in the step (2) into another reaction container to react at a temperature between -30 DEG C and 80 DEG C to obtain a reaction solution containing pentafluoroalkoxyl cyclotriphosphazene; (4) rectifying the reaction solution obtained inthe step (3) to obtain the pentafluoroalkoxyl cyclotriphosphazene. The method provided by the invention has the advantages of less side reactions and high yield of pentafluoroalkoxyl cyclotriphosphazene, has the high yield higher than 62%, and is suitable for industrial large-scale production.
A Fluorination Method for Phosphonitrilic Chloride Trimer and Its Derivatives
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Paragraph 0018, (2018/05/17)
The present invention relates to a fluorination method for phosphonitrilic chloride trimer and its derivatives including using phosphonitrilic chloride or partially substituted phosphonitrilic chloride trimer as raw material to fluorinate with fluoridating agent in an ionic liquid to replace the chlorine in chloro-cyclotiphosphazene molecule. The present invention uses non-volatile and pollution free ionic liquids as solvent, and just controls a distillation temperature to get a hexafluorocyclotriphosphazene or derivatives thereof with high-purity. It overcomes the shortcoming of the average solvent system that the solvent forms azeotrope with products. The post-process is simple. The production rate is high, and the ionic liquid can be recycled. The present invention produces products with high purity.