33143-50-9

Basic information

• Product Name: Carbamic acid, (1,3-diphenyl-2-propenyl)-, methyl ester, (E)-
• CAS NO: 33143-50-9
• Molecular Formula: C17H17NO2
• Molecular Weight: 267.327
• Mol File: 33143-50-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (1,3-diphenyl-2-propenyl)-, methyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (1,3-diphenyl-2-propenyl)-, methyl ester, (E)-(33143-50-9)
• EPA Substance Registry System: Carbamic acid, (1,3-diphenyl-2-propenyl)-, methyl ester, (E)-(33143-50-9)

Safety Data

• Hazardous Substances Data: 33143-50-9(Hazardous Substances Data)

Upstream product

• 3412-44-0 1,3-diphenylpropene 
• 598-55-0 methyl carbamate 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 

Relevant articles and documents

Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides

(Figure Presented) No preactivation of the alcohol substrates is required in allylic, propargylic, and benzylic aminations catalyzed by a combination of commercially available Bi(OTf)3 and KPF6, mostly at room temperature (see scheme). The substitution reactions of readily accessible allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides give the desired amine products in up to 99% yield.

Aluminum triflate as a powerful catalyst for direct amination of alcohols, including electron-withdrawing group-substituted benzhydrols

Direct aminations of allylic alcohols, benzylic alcohols, and benzhydrols with electron-withdrawing (F, Br, I, NO2, or CN) substituents were efficiently catalyzed by aluminum triflate [Al(OTf)3] to afford the corresponding biarylamines in high yield, and the dibromo-substituted product was further transformed into letrozole. Copyright