331456-61-2Relevant articles and documents
Synthesis of phalluside-1 and Sch II using 1,2-metallate rearrangements
Black, Fiona J.,Kocienski, Philip J.
supporting information; scheme or table, p. 1188 - 1193 (2010/06/15)
(4E,8E,10E)-9-Methyl-4,8,10-sphingatrienine, a core component of marine sphingolipids, was synthesised for the first time using a copper(i)-mediated 1,2-metallate rearrangement of a lithiated glycal as a key step. It was converted to phalluside-1, a cereb