33155-61-2

Basic information

• Product Name: tert-butyl 2-(4-methoxyphenyl)acetate
• Synonyms: tert-butyl 2-(4-methoxyphenyl)acetate
• CAS NO: 33155-61-2
• Molecular Weight: 222.284
• Mol File: 33155-61-2.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: tert-butyl 2-(4-methoxyphenyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 2-(4-methoxyphenyl)acetate(33155-61-2)
• EPA Substance Registry System: tert-butyl 2-(4-methoxyphenyl)acetate(33155-61-2)

Safety Data

• Hazardous Substances Data: 33155-61-2(Hazardous Substances Data)

Upstream product

• 64861-75-2 3,3-Dimethoxy-2-(4-methoxy-phenyl)-propionic acid tert-butyl ester 
• 104-01-8 4-Methoxyphenylacetic acid 
• 98946-18-0 tert-Butyl 2,2,2-trichloroacetimidate 
• 113680-16-3 diethyl (2-(4-methoxyphenyl)-2-oxoethyl) phosphate 
• 75-65-0 tert-butyl alcohol 
• 4693-91-8 4-methoxyphenyl-acetic chloride 
• 1694-31-1 tert-butyl acetoacetate 
• 5292-43-3 bromoacetic acid tert-butyl ester 
• 623-12-1 4-chloromethoxybenzene 
• 123-11-5 4-methoxy-benzaldehyde 
• 60512-57-4 1-(2,2-dibromovinyl)-4-methoxybenzene 
• 24424-99-5 di-tert-butyl dicarbonate 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 51656-70-3 (2-tert-butoxy-2-oxoethyl)zinc(II) bromide 

Downstream Products

• 108-94-1 cyclohexanone 
• 93831-11-9 4-Hydroxy-3-(4-methoxyphenyl)-furan-2(5H)-one 
• 27737-94-6 tert-butyl α-bromo-(p-methoxyphenyl)acetate 
• 85277-61-8 1-tert-butyl 3-ethyl 2-(4-methoxyphenyl)malonate 
• 85277-94-7 (E)-3-fluoro-2-(4-methoxyphenyl)prop-2-en-1-ol 
• 85277-85-6 (E)-ethyl 3-fluoro-2-(4-methoxyphenyl)acrylate 
• 85278-03-1 (E)-1-Fluoro-2-(4'-methoxy)phenyl-3-phthalimidopropene 
• 85277-72-1 1-tert-butyl 3-ethyl 2-(difluoromethyl)-2-(4-methoxyphenyl)malonate 
• 85278-11-1 (E)-3-Fluoro-2-(4-methoxy-phenyl)-allylamine; hydrochloride 
• 76529-97-0 (E)-2,3-Bis-(4-methoxy-phenyl)-but-2-enedioic acid di-tert-butyl ester 
• 76529-96-9 2-Bromo-2,3-bis-(4-methoxy-phenyl)-succinic acid di-tert-butyl ester 
• 76529-93-6 tert-butyl 3-<(tert-butoxycarbonyl)amino>-p-methoxy-3-aminonocardicinate 
• 76529-90-3 tert-butyl 3-<(tert-butoxycarbonyl)amino>-p-methoxy-3-aminonocardicinate 
• 76530-00-2 tert-butyl α-diazo-α-4-methoxyphenylacetate 

Relevant articles and documents

Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E?H Bonds

A new method for the synthesis of chiral diene rhodium catalysts is introduced. The readily available racemic tetrafluorobenzobarrelene complexes [(R2-TFB)RhCl]2 were separated into two enantiomers via selective coordination of one of them with the auxiliary S-salicyl-oxazoline ligand. One of the resulting chiral complexes with an exceptionally bulky diene ligand [(R,R-iPr2-TFB)RhCl]2 was an efficient catalyst for the asymmetric insertion of diazoesters into B?H and Si?H bonds giving the functionalized organoboranes and silanes with high yields (79–97 %) and enantiomeric purity (87–98 % ee). The stereoselectivity of separation via auxiliary ligand and that of the catalytic reaction was predicted by DFT calculations.

Complexes

A palladium(II) complex of formula (1) or a palladium(II) complex of formula (3). Also, processes for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.

Copper-catalyzed coupling of aryl iodides and tert-butyl keto esters: Efficient access to α-aryl ketones and α-arylacetic acid tert-butyl esters

CuI/trans-4-hydroxy-l-proline catalyzed coupling of aryl iodides with tert-butyl keto esters proceeded smoothly at 40 °C in DMF, providing α-aryl ketones after acid-promoted deprotection and decarboxylation of tert-butyl ester group. While CuI/2-picolinic acid catalyzed coupling of aryl iodides with tert-butyl acetoacetate at 70 °C in dioxane delivered α-arylacetic acid tert-butyl esters upon spontaneous deacylation. A wide range of functional groups, such as acetyl, methoxy, nitrile, nitro, bromo, and chloro were compatible with the reaction conditions.