33206-56-3Relevant articles and documents
Synthesis of new nano schiff base complexes: X-Ray crystallography, thermal, electrochemical and anticancer studies of nano uranyl schiff base complexes
Firuzabadi, Fahimeh Dehghani,Asadi, Zahra,Yousefi, Reza
, p. 89 - 100 (2018)
This study presents synthesis and characterization of new nano uranyl Schiff base complexes. Electrochemistry of these complexes showed a quasireversible redox reaction without any successive reactions. Furthermore, X-ray crystallography exhibited that beside the coordination of tetradentate Schiff base, one solvent molecule (dimethylformamide) was also coordinated. According to Coats-Redfern plots the kinetics of thermal decomposition of the studied complexes was first-order in all stages. Anticancer activities of the uranyl Schiff base complexes against cancer cell lines (Jurkat) was studied and determined by MTT (3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazoliumbromide) assay. The results demonstrated that the complexes with aliphatic bridging units showed less anticancer activities than those having the aromatic units.
New sodium dodecyl sulfate-assisted preparation of Nd2O3 nanostructures via a simple route
Mortazavi-Derazkola, Sobhan,Zinatloo-Ajabshir, Sahar,Salavati-Niasari, Masoud
, p. 56666 - 56676 (2015)
The effect of the anionic shape- and size-controller on the morphology and size of Nd2O3 prepared by a new simple approach was studied. Nanostructured Nd2O3 was synthesized by heat treatment in air at 900 °C for 5 h, employing powder, which was prepared by a solvent-free solid-state reaction from [NdL(NO3)2]NO3 (L = bis-(2-hydroxy-1-naphthaldehyde)-ethanediamine Schiff base compound), as a new precursor, in the presence of sodium dodecyl sulfate (SDS) as shape- and size-controller. The structural, morphological and optical properties of the as-obtained nanostructured Nd2O3 were characterized by thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), energy dispersive X-ray microanalysis (EDX), UV-vis diffuse reflectance spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and Fourier transform infrared (FT-IR) spectroscopy. The obtained results demonstrated that the amount of SDS plays a key role in the morphology and particle size control of the neodymium oxide. Furthermore, the catalytic properties of the as-prepared nanostructures were evaluated by the photocatalytic degradation of the erythrosine (anionic dye) as water contaminant.
Temperature and frequency dependent dielectric properties of electrically conducting oxidatively synthesized polyazomethines and their structural, optical, and thermal characterizations
Dineshkumar, Sengottuvelu,Muthusamy, Athianna,Chandrasekaran
, p. 730 - 740 (2016/09/28)
Three azomethine diol monomers were synthesized by condensing with methanolic solution of aromatic aldehydes with ethylenediamine. These monomers were oxidatively polymerized using NaOCl as an oxidant. The structures of the monomers and polymers were conf