332402-98-9Relevant articles and documents
Palladium-catalyzed highly regioselective hydroaminocarbonylation of aromatic alkenes to branched amides
Zhu, Jinping,Gao, Bao,Huang, Hanmin
supporting information, p. 2910 - 2913 (2017/04/11)
Pd(t-Bu3P)2 has been successfully identified as an efficient catalyst for the hydroaminocarbonylation of aromatic alkenes to branched amides under relatively mild reaction conditions. With hydroxylamine hydrochloride as an additive,
Ru-catalyzed hydroamidation of alkenes and cooperative aminocarboxylation procedure with chelating formamide
Ko, Sangwon,Han, Hoon,Chang, Sukbok
, p. 2687 - 2690 (2007/10/03)
(Matrix presented) A strategy of chelation-assisted activation of formamide was employed to achieve hydroamidation of alkenes to generate one-carbon-elongated amides in moderate to good selectivity and yields. Also reported is the two-metal-catalyzed cooperative aminocarboxylation of aryl iodides, in which Ru is presumed to catalyze decarbonylation of formamide to release carbon monoxide and amine for the subsequent Pd-catalyzed aminocarboxylation routes, thus enabling the net transformation to be performed in the absence of external CO pressure.