332411-27-5Relevant articles and documents
Phenanthrene-containing phenanthroimidazole luminescent material as well as preparation method and application thereof
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Paragraph 0008; 0030-0031, (2021/10/27)
The invention relates to a phenanthrene-containing phenanthroimidazole luminescent material as well as a preparation method and application thereof. With the carbonyl compound and diethyl (4 -cyanobenzyl) phosphonate as raw materials, the Wittig-Honor reaction is carried out. Redox reaction, debus-radziszewski ' one-pot process' produces phenanthrene-containing phenanthrene compounds. The method can utilize the characteristic infrared absorption of formyl and cyano in the infrared spectrum to monitor the reaction process. A precious metal catalysis carbon-carbon coupling reaction is avoided in the reaction process. And yield is high. The invention provides a new method for synthesizing phenanthrene-containing phenanthrene compounds. In addition, the phenanthrene-containing phenanthroimidazole compound provided by the invention can be directly applied to ultraviolet excited organic/inorganic hybrid white LED devices as an organic luminescent material, and a technical reference is provided for application thereof.
STILBENE DERIVATIVES FOR THE TREATMENT OF CNS AND OTHER DISORDERS
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, (2018/12/03)
The present application discloses stilbene derivative compounds and compositions, and methods for treating ocular diseases, neurological disorders and protein aggregation-related disorders in patients using the compounds and compositions as disclosed herein.
Degradation of cyanoacrylic acid-based organic sensitizers in dye-sensitized solar cells
Chen, Cheng,Yang, Xichuan,Cheng, Ming,Zhang, Fuguo,Sun, Licheng
, p. 1270 - 1275 (2013/07/26)
Organic dyes have become widely used in dye-sensitized solar cells (DSSCs) because of their good performance, flexible structural modifications, and low costs. To increase the photostability of organic dye-based DSSCs, we conducted a full study on the degradation mechanism of cyanoacrylic acid-based organic sensitizers in DSSCs. The results showed that with the synergy between water and UV light, the sensitizer could desorb from the TiO2 surface and the cyanoacrylic acid unit of the sensitizer was transformed into the aldehyde group. It was also observed that the water content had a great effect on the degradation process. Our experiments conducted using 18O-labeled water demonstrated that the oxygen atom of the aldehyde group identified in the degraded dye came from the solvent water in the DSSCs. Therefore, controlling the water content during DSSC fabrication, good sealing of cells, and filtering the UV light are crucial to produce DSSCs that are more durable and robust. Dye-ing to degrade: The degradation mechanism of cyanoacrylic acid-based organic sensitizers in dye-sensitized solar cells (DSSCs) has been studied. With the synergy of water and UV light, the sensitizer desorbs from the TiO2 surface and the cyanoacrylic acid unit of sensitizer is converted into an aldehyde group. It is also observed that the oxygen atom of the aldehyde comes from the solvent water in DSSCs. Copyright