33489-63-3Relevant articles and documents
Nickel-catalyzed remote hydrosilylation of unconjugated enones with bulky triphenylsilane
Chen, Xue,Jin, Hongwei,Liu, Yunkui,Wang, Zhen,Zhou, Bingwei,Zhou, Jinyong
, p. 8021 - 8024 (2021/10/04)
Herein we describe a nickel-catalyzed remote hydrosilylation of unconjugated enones with bulky triphenylsilane. A range ofZ-silyl enol ethers are obtained as major isomers due to the process of nickel triggered alkene isomerization. Notably, some specific
Highly chemoselective and versatile method for direct conversion of carboxylic acids to ketones utilizing zinc Ate complexes
Murata, Ryo,Hirano, Keiichi,Uchiyama, Masanobu
supporting information, p. 1286 - 1290 (2015/06/08)
Various carboxylic acids were directly transformed into the corresponding ketones by utilizing organozinc ate complexes, which provide high chemoselectivity without any overreaction to the undesired tertiary carbinol, owing to formation of a stable tetrahedral zincioketal intermediate. This method offers good overall atom/step/pot economy and operational simplicity. No need to overreact: Various carboxylic acids were directly transformed to the corresponding ketones by utilizing organozinc ate complexes, which provide high chemoselectivity without any overreaction to undesired tertiary carbinol, owing to formation of a stable tetrahedral zincioketal intermediate. This method offers good overall atom/step/pot economy and operational simplicity.
1,3-Dithiane polymers for the supported synthesis of ketones
Bertini, Vincenzo,Lucchesini, Francesco,Pocci, Marco,De Munno, Angela
, p. 9263 - 9266 (2007/10/03)
The synthesis of polymeric reagents containing an odorless propane-1,3- dithiol functionality is reported. Their usefulness for the solid phase synthesis of ketones via the umpoled alkylation of 1,3-dithianes is demonstrated.