3360-55-2Relevant articles and documents
Halofluorination of alkenes using trihaloisocyanuric acids and HF-pyridine
Crespo, Livia T. C.,Ribeiro, Rodrigo Da S.,De Mattos, Marcio C. S.,Esteves, Pierre M.
experimental part, p. 2379 - 2382 (2010/09/04)
Halofluorination of alkenes with a new system (trihaloisocyanuric acids and HF-pyridine) results in the formation of vicinal halofluoroalkanes. The reaction is regioselective leading to Markovnikov-oriented products and the halofluorinated adducts follow anti-addition in the case of cyclohexene and 1-methylcyclohexene. Reaction yields range from 67-88%. Georg Thieme Verlag Stuttgart · New York.
Reactions of Copper(I) Halide Complexes of Trivalent Phosphorus with Vinylic Halides
Axelrad, George,Laosooksathit, Surin,Engel, Robert
, p. 5200 - 5204 (2007/10/02)
The direct formation of the vinylic carbon to phosphorus bond has been accomplished via reaction of vinylic halides with copper(I) halide complexes of trialkyl phosphites.In addition, formation of varying amounts of vinylic chlorides may be observed if the reaction is performed by using vinylic bromides with copper(I) chloride complexes of trialkyl phosphites.This halogen-exchange reaction may be made synthetically useful through the employment of copper(I) chloride complexes of triaryl phosphites or phosphines.
