33647-67-5Relevant articles and documents
Asymmetric synthesis of methyl 6-deoxy-3-O-methyl-α-l-mannopyranoside from a non-carbohydrate precursor
Du, Wenting,Hu, Yongzhou
, p. 725 - 729 (2007/10/03)
A novel method is reported for preparing methyl 6-deoxy-3-O-methyl-α- l-mannopyranoside (1) by asymmetric synthesis, using 2-acetylfuran (2), a non-chiral simple molecule, as the starting material and achieving high yields via (S)-1-(2-furyl)ethanol and (
Electroorganic synthesis of 2,5-dialkoxydihydrofurans and pyridazines on solid phase using polymer beads as supports
Nad, Sukanya,Breinbauer, Rolf
, p. 3654 - 3665 (2007/10/03)
Electroorganic synthesis has defied application in Solid-Phase Organic Synthesis (SPOS) so far. Typically more than 99.9% of the substrate molecules immobilized on a polymeric support are buried in the interior of the bead, and therefore are unable to undergo direct contact with a heterogeneous reagent such as an electrode. This intrinsic impediment for an electrochemical reaction can be overcome by the use of a redox mediator which shuttles electrons from the electrode to the polymer bound substrate molecules. This approach of indirect electroorganic synthesis was successfully applied for the 2,5-dialkoxylation of furans on solid phase. The oxidation products can be hydrolyzed and through condensation with hydrazine hydrate substituted pyridazines are produced in 50-65% overall yield. Georg Thieme Verlag Stuttgart.
Synthesis of 1-(2,5-dimethoxy-2,5-dihydrofuran-2-yl)ethanol from 2-acetylfuran
Smigielski,Kaminska,Gora
, p. 369 - 371 (2007/10/03)
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