33686-67-8

Basic information

• Product Name: 9-(α-bromo-α-p-methoxyphenylmethylene)fluorene
• Synonyms: 9-(α-bromo-α-p-methoxyphenylmethylene)fluorene
• CAS NO: 33686-67-8
• Molecular Weight: 363.253
• Mol File: 33686-67-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 9-(α-bromo-α-p-methoxyphenylmethylene)fluorene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(α-bromo-α-p-methoxyphenylmethylene)fluorene(33686-67-8)
• EPA Substance Registry System: 9-(α-bromo-α-p-methoxyphenylmethylene)fluorene(33686-67-8)

Safety Data

• Hazardous Substances Data: 33686-67-8(Hazardous Substances Data)

Upstream product

• 86-73-7 9H-fluorene 
• 123-11-5 4-methoxy-benzaldehyde 
• 33686-69-0 9-Anisylidenfluoren Dibromid 
• 2871-87-6 p-methoxybenzylidene fluorene 

Downstream Products

• 105791-38-6 2-<4-Methoxy-phenyl>-1,1,3,3-bis-biphenylen-propen-(1) 
• 33686-73-6 α-Ethoxy-9-anisylidenfluoren 
• 33735-94-3 α-Acetoxy-9-anisylidenfluoren 
• 33686-74-7 α-p-Toluenthio-9-anisylidenfluoren 
• 52789-61-4 2-(4-Methoxy-phenyl)-1,1,3,3-bis-biphenylen-allyl 
• 33686-75-8 α-Benzylthio-9-anisylidenfluoren 
• 80310-53-8 C₃₁H₁₉NO₃ 
• 486-25-9 9-fluorenone 
• 2871-87-6 p-methoxybenzylidene fluorene 

Relevant articles and documents

Light-Induced Intramolecular Iodine-Atom Transfer Radical Addition of Alkyne: An Approach from Aryl Iodide to Alkenyl Iodide

A light-induced intramolecular iodine-atom transfer radical addition was reported toward iodine-substituted fluorene derivatives. A thioxanthone derivative was employed as a visible light sensitizer for this 5-exo-dig exclusive radical addition, and the newly formed vinyl iodide compounds were further proved to be effective partners for several cross-coupling reactions.

Diels-Alder Reaction: 1,4-Cycloaddition of N-Aryl-maleimides to Alkylidene- and Arylidene-fluorenones and Synthesis of Some New Fluoranthene Derivatives

The 1,4-cycloaddition of different N-arylmaleimides (IIa-f) to alkylidene- and arylidene-fluorenones (Ia-c) leads to the formation of the diadducts, 7-substituted-5-aryl-4,6-dioxo-4H-3,3a,5,6,6a,7,10b-octahydrofluoranthenopyrrole-endo(3,10b)-N-arylpyrrolidino-2',5'-diones (IIIa-r).The fully aromatized fluoranthene derivatives (Va-i) have also been synthesised either by boiling III in nitrobenzene or by reacting the bromo-derivatives (V) with appropriate II.Reduction of III using LAH gives VIII.The structures of the isolated products have been confirmed by elemental analyses, molecular weight determination and spectroscopic data.