337376-51-9

Basic information

• Product Name: (1R,2R)-trans-1-Hydroxy-1,2-dihydro-2-naphthyl benzoate
• Synonyms: (1R,2R)-trans-1-Hydroxy-1,2-dihydro-2-naphthyl benzoate
• CAS NO: 337376-51-9
• Molecular Formula: C17H15O3
• Molecular Weight: 267.2992
• Mol File: 337376-51-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 448.2±45.0 °C(Predicted)
• Appearance: /
• Density: 1.27±0.1 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• PKA: 13.17±0.40(Predicted)
• CAS DataBase Reference: (1R,2R)-trans-1-Hydroxy-1,2-dihydro-2-naphthyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-trans-1-Hydroxy-1,2-dihydro-2-naphthyl benzoate(337376-51-9)
• EPA Substance Registry System: (1R,2R)-trans-1-Hydroxy-1,2-dihydro-2-naphthyl benzoate(337376-51-9)

Safety Data

• Hazardous Substances Data: 337376-51-9(Hazardous Substances Data)

Upstream product

• 573-57-9 1,4-epoxy-1,4-dihydronaphthalene 
• 1863-63-4 ammonium benzoate 
• 65-85-0 benzoic acid 

Relevant articles and documents

Rhodium/zinc co-catalyzed asymmetric ring opening reactions of oxabenzonorbornadienes with carboxylic acids

The asymmetric ring opening reactions of oxabenzonorbornadienes with carboxylic acids are described. By using the complex of [Rh(COD)Cl]2and (S,S)-BDPP, with ZnI2as the co-catalyst, a range of aromatic acids and alkyl acids were utilized as nucleophiles to afford the corresponding chiral hydronaphthalene products with high enantioselectivities (84–94% ee). Thus, the present methodology has provides an effective synthetic method for the preparation of enantioenriched hydronaphthalenes.

Hydronaphtalene compounds, prepared by a rhodium catalyzed ring opening reaction in the presence of phosphine ligand

The present invention is directed to a procedure for making an enantiomerically enriched compound containing a hydronaphthalene ring structure. The process involves reacting oxabenzonorbornadienes with nucleophiles using rhodium as a catalyst and in the p