33828-92-1Relevant articles and documents
A General Strategy to Enhance Donor-Acceptor Molecules Using Solvent-Excluding Substituents
Asbury, John B.,Hoelzel, Conner A.,Hu, Hang,Jung, Kwan Ho,Karim, Basel A.,Li, Xiaosong,Liu, Yu,Munson, Kyle T.,Wolstenholme, Charles H.,Yennawar, Hemant P.,Zhang, Han,Zhang, Xin
supporting information, p. 4785 - 4792 (2020/02/11)
While organic donor-acceptor (D-A) molecules are widely employed in multiple areas, the application of more D-A molecules could be limited because of an inherent polarity sensitivity that inhibits photochemical processes. Presented here is a facile chemical modification to attenuate solvent-dependent mechanisms of excited-state quenching through addition of a β-carbonyl-based polar substituent. The results reveal a mechanism wherein the β-carbonyl substituent creates a structural buffer between the donor and the surrounding solvent. Through computational and experimental analyses, it is demonstrated that the β-carbonyl simultaneously attenuates two distinct solvent-dependent quenching mechanisms. Using the β-carbonyl substituent, improvements in the photophysical properties of commonly used D-A fluorophores and their enhanced performance in biological imaging are shown.
Spiro-pyranic compounds endowed with photochromic characteristics
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, (2008/06/13)
Photochromic compounds belonging to the class of spiro-pyrans, having the general formula (I): STR1
Intermediates for preparing optically active carboxylic acids
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, (2008/06/13)
A process is described for preparing optically active alpha-arylalkanoic acids consisting of rearranging an optically active ketal of formula STR1 in which the substituents have the meaning given in the description of the invention.