33868-50-7Relevant articles and documents
Bioinspired Oxidative Cleavage of Aliphatic C–C Bonds Utilizing Aerial Oxygen by Nickel Acireductone Dioxygenase Mimics
Raje, Sakthi,Mani, Kalaikodikumaran,Kandasamy, Parameswaran,Butcher, Ray J.,Angamuthu, Raja
, p. 2164 - 2167 (2019)
Bioinspired oxidative cleavage of aliphatic C–C bonds of the acireductone model substrate 2-hydroxy-3-oxo-1,3-diphenylprop-1-en-1-olate, bound to two paramagnetic nickel(II) complexes that are mimics for the nickel containing acireductone dioxygenase, has been achieved utilizing aerial oxygen under ambient conditions.
Decarboxylative Oxyacyloxylation of Propiolic Acids: Construction of Alkynyl-Containing α-Acyloxy Ketones
Chen, Xin,Xin, Yangchun,Zhao, Zhi-Wei,Hou, Yu-Jian,Wang, Xiang-Xiang,Xia, Wen-Jin,Li, Ya-Min
supporting information, p. 8216 - 8225 (2021/06/28)
Novel decarboxylative oxyacyloxylation of propiolic acids has been developed. This reaction provides an efficient access to alkynyl-containing α-acyloxy ketones from readily available starting materials and exhibits significant functional group tolerance. Furthermore, oxyacyloxylation of terminal alkynes and aliphatic propiolic acids was also developed. A possible reaction mechanism is proposed based on mechanistic studies.
Aerobic Photooxidative Synthesis of β-Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base
Asano, Yuya,Nagasawa, Yoshitomo,Yamaguchi, Eiji,Itoh, Akichika
supporting information, p. 409 - 412 (2018/02/21)
Transition-metal-free synthesis of β-alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost-effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system.
