33877-04-2

Basic information

• Product Name: 2-Propenoic acid, 3-(3-methoxyphenyl)-, ethyl ester
• CAS NO: 33877-04-2
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 33877-04-2.mol
• Article Data: 90

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(3-methoxyphenyl)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(3-methoxyphenyl)-, ethyl ester(33877-04-2)
• EPA Substance Registry System: 2-Propenoic acid, 3-(3-methoxyphenyl)-, ethyl ester(33877-04-2)

Safety Data

• Hazardous Substances Data: 33877-04-2(Hazardous Substances Data)

Usage

Physical State

Colorless or pale yellow liquid

Odor

Characteristic fruity odor

Main Uses

Production of fragrances and flavors
Synthesis of pharmaceuticals and other organic compounds
Monomer in polymer industry for various polymers
Intermediate in organic synthesis for chemical products preparation

Upstream product

• 1711-05-3 m-anisoyl chloride 
• 140-88-5 ethyl acrylate 
• 65946-56-7 1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene 
• 591-31-1 3-methoxy-benzaldehyde 
• 6971-51-3 3-methoxybenzyl alcohol 
• 105-36-2 ethyl bromoacetate 
• 2398-37-0 3-methoxyphenyl bromide 
• 105273-30-1 m-methoxyphenyl 2-(1,1,2,2-tetrafluoroethoxy)-1,1,2,2-tetrafluoroethanesulphonate 
• 150-19-6 O-methylresorcine 
• 3699-71-6 o-ethyl-phenyl-2-carbethoxymethyl phosphinate 
• 6361-05-3 ethyl 2-(diphenylphosphoryl)acetate 
• 72258-75-4 2-<(ethoxycarbonyl)methyl>-2-oxo-4,5-dimethyl-1,3,2-dioxaphospholane 
• 64-17-5 ethanol 
• 141-82-2 malonic acid 

Downstream Products

• 42766-21-2 5-(3-methoxyphenyl)-1,2-dithiole-3-one 
• 1268132-13-3 trans-3-(3-methoxy-phenyl)-2,2-dimethyl-cyclopropanecarboxylic acid 
• 1435743-60-4 (E)-diethyl [3-(3-methoxyphenyl)allyl] phosphate 
• 1433413-03-6 (E)-1,2,3,4,5-pentafluoro-6-(3-(3-methoxyphenyl)allyl)benzene 
• 1202207-29-1 (E)-1-methoxy-3-(3-phenoxyprop-1-en-1-yl)benzene 
• 94146-33-5 2,4-dicarbethoxy-3-(3-methoxyphenyl)-1-oxo-1,2,3,4-tetrahydronaphthalene 
• 94146-18-6 2-(2-Carboxy-phenyl)-3-(3-methoxy-phenyl)-pentanedioic acid 
• 94146-72-2 3-(3-Methoxy-phenyl)-2-naphthalen-2-yl-pentanedioic acid 
• 94146-41-5 2-(3-methoxyphenyl)-1,2,3,4-tetrahydrophenanthrene-1-carboxylic acid 
• 94146-80-2 1-carboxy-2-(3-methoxyphenyl)-4-oxo-1,2,3,4-tetrahydrophenanthrene 
• 94146-60-8 3-(3-Methoxy-phenyl)-2-phenyl-pentanedioic acid 
• 94146-76-6 4-carboxy-3-(3-methoxyphenyl)-1-oxo-1,2,3,4-tetrahydronaphthalene 

Relevant articles and documents

Electrochemical Generation of a Nonstabilized Azomethine Ylide: Access to Substituted N-Heterocycles

Azomethine ylides are fascinating 1,3-dipoles for [3 + 2] cycloaddition reactions toward the construction ofN-heterocycles. Herein, an efficient and environmentally benign electrochemical approach for the generation of a nonstabilized azomethine ylide has been established under metal-free and external oxidant-free conditions. The resulting 1,3-dipole undergoes a [3 + 2] cycloaddition reaction with olefins. This electrosynthetic methodology indulges a straightforward and facile approach for the construction of substituted pyrrolidines.

Synthesis of Bidentate Nitrogen Ligands by Rh-Catalyzed C-H Annulation and Their Application to Pd-Catalyzed Aerobic C-H Alkenylation

A new class of bidentate ligands was prepared by a modular approach involving Rh-catalyzed C-H annulation reactions. The resulting conformationally constrained ligands enabled the Pd-catalyzed C-H alkenylation at electron-rich and sterically less hindered positions of electron-rich arenes while promoting the facile oxidation of Pd(0) intermediates by oxygen. This newly introduced ligand class is complementary to the ligands developed for Pd-catalyzed oxidative reactions and may find broad application in transition-metal-catalyzed reactions.

Intramolecular Sakurai Allylation of Geminal Bis(silyl) Enamide with Indolenine. A Diastereoselective Cyclization to Form Functionalized Hexahydropyrido[3,4- b]Indole

A fluoride-promoted intramolecular Sakurai allylation of geminal bis(silyl) enamide with indolenine has been developed. The reaction facilitates an efficient cyclization to give hexahydropyrido[3,4-b]indoles in good yields with high diastereoselectivity. The resulted cis, trans-stereochemistry further enables the ring-closing metathesis (RCM) reaction of two alkene moieties, giving a tetracyclic N-hetereocycle widely found as the core structure in akuammiline alkaloids.