339148-74-2

Basic information

• Product Name: (1R,2S,E)-ethyl 2-hydroxy-1-(6-benzyloxy-4-hexenyl)cyclopentane-1-carboxylate
• Synonyms: (1R,2S,E)-ethyl 2-hydroxy-1-(6-benzyloxy-4-hexenyl)cyclopentane-1-carboxylate
• CAS NO: 339148-74-2
• Molecular Weight: 346.467
• Mol File: 339148-74-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S,E)-ethyl 2-hydroxy-1-(6-benzyloxy-4-hexenyl)cyclopentane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,E)-ethyl 2-hydroxy-1-(6-benzyloxy-4-hexenyl)cyclopentane-1-carboxylate(339148-74-2)
• EPA Substance Registry System: (1R,2S,E)-ethyl 2-hydroxy-1-(6-benzyloxy-4-hexenyl)cyclopentane-1-carboxylate(339148-74-2)

Safety Data

• Hazardous Substances Data: 339148-74-2(Hazardous Substances Data)

Upstream product

• 339148-68-4 (E)-1-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-hexene 
• 339148-69-5 (E)-6-benzyloxy-4-hexen-1-ol 
• 611-10-9 2-ethoxycarbonyl-1-cyclopentanone 
• 100-39-0 benzyl bromide 
• 61586-79-6 ethyl (1R,2S)-2-hydroxycyclopentanecarboxylate 
• 339148-64-0 (E)-1-benzyloxy-6-iodo-2-hexene 
• 98897-64-4 (E)-6-[(tert-butyldimethylsilyl)oxy]-2-hexen-1-ol 

Downstream Products

• 339148-80-0 (1S,5R,E)-5-(6-benzyloxy-4-hexenyl)-2-oxa-4-azabicyclo[2.2.0]octan-3-one 

Relevant articles and documents

Synthetic studies on halichlorine and pinnaic acid: Palladium-mediated construction of the bicyclic spiro core

Palladium-mediated cyclization of 19 and 23 directed toward the construction of the bicyclic core (3), which would serve as a key intermediate for the total synthesis of halichlorine (1) and pinnaic acid (2), was explored and found to proceed for 19 in a