33915-37-6

Basic information

• Product Name: trans-{PtH(CO)(PPh₃)2}BF₄
• Synonyms: trans-{PtH(CO)(PPh₃)2}BF₄
• CAS NO: 33915-37-6
• Molecular Weight: 835.485
• Mol File: 33915-37-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-{PtH(CO)(PPh₃)2}BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: trans-{PtH(CO)(PPh₃)2}BF₄(33915-37-6)
• EPA Substance Registry System: trans-{PtH(CO)(PPh₃)2}BF₄(33915-37-6)

Safety Data

• Hazardous Substances Data: 33915-37-6(Hazardous Substances Data)

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 203259-76-1 cis-[Pt(difluoroboryl)2(PPh₃)2] 
• 201230-82-2 carbon monoxide 
• 75-65-0 tert-butyl alcohol 

Relevant articles and documents

Transition metal complexes incorporating the BF2 ligand formed by oxidative addition of the B-B bond in B2F4

The reactions between B2F4 and the platinum and iridium complexes [Pt(PPh3)2(η-C2H4)], [Pt(dppb)(r)-C2H4)] [dppb = l,4-bis(diphenylphosphino)butane] and trans-[IrCl(CO)(PPh3)2] afforded the difluoroboryl complexes cis-[Pt(BF2)2(PPh3)2], cis-[Pt(BF2)2(dppb)] and fac-[Ir(BF2)3(CO)(PPh3)2] respectively all of which have been characterised by X-ray crystallography. The isoelectronic platinum dppb nitrito complex cw-[Pt(NO2)2(dppb)] has also been prepared and structurally characterised. The Royal Society of Chemistry 2000.