34044-18-3

Basic information

• Product Name: butyl(trimethylsilyl)selane
• Synonyms: butyl(trimethylsilyl)selane
• CAS NO: 34044-18-3
• Molecular Weight: 209.265
• Mol File: 34044-18-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: butyl(trimethylsilyl)selane(CAS DataBase Reference)
• NIST Chemistry Reference: butyl(trimethylsilyl)selane(34044-18-3)
• EPA Substance Registry System: butyl(trimethylsilyl)selane(34044-18-3)

Safety Data

• Hazardous Substances Data: 34044-18-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 55163-69-4 lithium n-butylselenolate 

Relevant articles and documents

Synthesis and NMR investigation of selenobutyl substituted silanes and oligosilanes

The reaction of BuSeLi, made from BuLi and elemental selenium, with chlorosilanes MexPhySiCl4-x-y led to selenobutyl substituted derivatives. In the cases of polychlorosilanes formation of the completely substituted products MexPhySi(SeBu)4-x-y are favoured. Higher yields of partially substituted products could be obtained by reaction of chlorosilanes with BuSeH/NEt3. Besides monosilanes the reactions of several methylchlorodi-, tri- and isotetrasilanes with BuSeLi and BuSeH/NEt3 were also investigated. In SiClMe(SiClMe2)2 the chlorine substituent at the middle silicon atom is substituted by BuSeH/NEt3 at first selectively. All products were characterized by 1H, 13C, 29Si and 77Se NMR and trends of chemical shifts and coupling constants (1JSiSi, 1JSiSe, 2JSiSe) with the substitution pattern were investigated. Wiley-VCH Verlag GmbH, 2000.