34085-09-1Relevant articles and documents
Divergent and Stereocontrolled Synthesis of the Enamide Side Chains of Oximidines I/II/III, Salicylihalamides A/B, Lobatamides A/D, and CJ-12,950
Coleman, Robert S.,Liu, Pei-Hua
, p. 577 - 580 (2004)
(Matrix presented) A unified strategy for the divergent and stereocontrolled introduction of the (E)- and (Z)-enamide side-chains of oximidines I, II, and III, salicylihalamides A and B, lobatamides A and D, and CJ-12,950 is detailed. The synthesis relied on the copper-promoted C-N coupling of (E)-and (Z)-vinyl iodides with a protected maleimide hemiaminal followed by deprotection and reaction of the resulting (E)- or (Z)-enelactam hemiaminals with O-methylhydroxylamine or propylidenetriphenylphosphorane.
Regioselective reduction of maleimide and citraconimide derivatives: General preparation of 5-hydroxy-1,5-dihydropyrrol-2-one
Mase, Nobuyuki,Nishi, Toshiki,Hiyoshi, Masaomi,Ichihara, Kazuhiro,Bessho, Junichiro,Yoda, Hidemi,Takabe, Kunihiko
, p. 707 - 709 (2007/10/03)
NaBH4 reduction of citraconimide derivatives regioselectively afforded 5-hydroxy-4-methyl-1,5-dihydropyrrol-2-ones, whereas NaBH4-CeCl3 or DIBAL-H reduction gave 5-hydroxy-3-methyl-1,5-dihydropyrrol-2-ones.
Determination of the absolute configuration of 3-pyrrolin-2-ones
Cuiper,Brzostowska,Gawronski,Smeets,Spek,Hiemstra,Kellogg,Feringa
, p. 2567 - 2570 (2007/10/03)
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