3412-59-7Relevant articles and documents
Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes
Chauhan, Bhanu P. S.,Sarkar, Alok
, p. 8709 - 8715 (2017/07/24)
A mild, selective and facile synthesis of vinylsilanes via a recyclable platinum nanoparticle catalysed hydrosilylation of alkynes is reported. Various functionalized alkynes are selectively hydrosilylated to furnish functional β-E vinylsilanes in high yi
Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies
Ortega-Moreno, Laura,Peloso, Riccardo,Maya, Celia,Suárez, Andrés,Carmona, Ernesto
supporting information, p. 17008 - 17011 (2015/12/01)
A novel terphenylphosphine PMe2ArDipp2 (1) (Dipp = 2,6-iPr2C6H3) forms stable Pt(0) complexes with ethene and 3,3-dimethylbut-1-ene that behave as sources of the reactive Pt(PMe
The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins
Pietraszuk, Cezary,Fischer, Helmut,Rogalski, Szymon,Marciniec, Bogdan
, p. 5912 - 5921 (2007/10/03)
Efficient cross-metathesis of vinylsilanes, carrying a large spectrum of different substituents at silicon, with various olefins in the presence of the first and second generation Grubbs catalyst and Hoveyda-Grubbs catalyst is described. On the basis of the results of equimolar reactions of vinylsilanes with ruthenium alkylidene complexes and experiments with deuterium-labelled reagents, a general, metallacarbene mechanism for the cross-metathesis of trisubstituted vinylsilanes with olefins has been suggested. Reaction was proved to be a valuable method for synthesis of unsaturated organosilicon derivatives.