341535-03-3

Basic information

• Product Name: trans-4-hydroxy-4-methylcyclohexyl acetate
• Synonyms: trans-4-hydroxy-4-methylcyclohexyl acetate
• CAS NO: 341535-03-3
• Molecular Weight: 172.224
• Mol File: 341535-03-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: trans-4-hydroxy-4-methylcyclohexyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: trans-4-hydroxy-4-methylcyclohexyl acetate(341535-03-3)
• EPA Substance Registry System: trans-4-hydroxy-4-methylcyclohexyl acetate(341535-03-3)

Safety Data

• Hazardous Substances Data: 341535-03-3(Hazardous Substances Data)

Upstream product

• 15876-34-3 trans-4-methylcyclohexyl acetate 
• 17429-02-6 4-hydroxy-4-methylcyclohexanone 
• 108-24-7 acetic anhydride 
• 124899-25-8 (1s,4s)-1-methylcyclohexane-1,4-diol 

Relevant articles and documents

Catalyst-controlled aliphatic C—H oxidations

The invention provides simple small molecule, non-heme iron catalyst systems with broad substrate scope that can predictably enhance or overturn a substrate's inherent reactivity preference for sp3-hybridized C—H bond oxidation. The invention also provides methods for selective aliphatic C—H bond oxidation. Furthermore, a structure-based catalyst reactivity model is disclosed that quantitatively correlates the innate physical properties of the substrate to the site-selectivities observed as a function of the catalyst. The catalyst systems can be used in combination with oxidants such as hydrogen peroxide to effect highly selective oxidations of unactivated sp3 C—H bonds over a broad range of substrates.

Highly efficient conversion of alcohols to isocyanides

Treatment of tertiary alcohols with silver salts (AgClO4, AgBF4, or AgOTf) and trimethylsilyl cyanide (TMSCN), followed by hydrolysis, directly affords excellent yields of corresponding isocyanides. This reaction proceeds selectively