3419-66-7 Usage
Description
1-TERT-BUTYL-1-CYCLOHEXENE is an organic compound that is characterized by its unique molecular structure, which features a cyclohexene ring with a tert-butyl group attached to it. 1-TERT-BUTYL-1-CYCLOHEXENE is known for its potential applications in various industries due to its chemical properties.
Uses
1. Used in Catalyst Research:
1-TERT-BUTYL-1-CYCLOHEXENE is used as a substrate to investigate the catalytic activity and BET (Brunauer-Emmett-Teller) surface area of different desilicated TS-1 zeolite samples. This application is significant in the field of catalysis, as it helps researchers understand the efficiency and effectiveness of various zeolite catalysts in chemical reactions.
2. Used in Chemical Synthesis:
1-TERT-BUTYL-1-CYCLOHEXENE can be utilized as an intermediate in the synthesis of various chemicals and pharmaceuticals. Its unique structure allows for further functionalization and modification, making it a valuable building block in the development of new compounds with specific properties and applications.
3. Used in Material Science:
1-TERT-BUTYL-1-CYCLOHEXENE may also find applications in material science, particularly in the development of new polymers and materials with tailored properties. Its cyclohexene ring and tert-butyl group can contribute to the overall structure and characteristics of the resulting materials, potentially leading to innovative applications in various industries.
4. Used in Analytical Chemistry:
1-TERT-BUTYL-1-CYCLOHEXENE can be employed as a reference compound or standard in analytical chemistry, particularly in techniques such as gas chromatography and mass spectrometry. Its distinct chemical properties make it suitable for calibrating instruments and validating analytical methods.
Synthesis Reference(s)
The Journal of Organic Chemistry, 36, p. 3826, 1971 DOI: 10.1021/jo00823a611Synthesis, p. 147, 1971 DOI: 10.1055/s-1971-21684
Check Digit Verification of cas no
The CAS Registry Mumber 3419-66-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,4,1 and 9 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 3419-66:
(6*3)+(5*4)+(4*1)+(3*9)+(2*6)+(1*6)=87
87 % 10 = 7
So 3419-66-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H18/c1-10(2,3)9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
3419-66-7Relevant articles and documents
Enantioselective Hydroazidation of Trisubstituted Non-Activated Alkenes
Meyer, Daniel,Renaud, Philippe
supporting information, p. 10858 - 10861 (2017/08/30)
A one-pot procedure for the enantioselective hydroazidation of non-activated trisubstituted alkenes is described. Hydroboration with monoisopinocampheylborane (IpcBH2) provides dialkylboranes that are in situ selectively converted into monoalkyl-substituted catecholboranes; these undergo radical azidation upon treatment with benzenesulfonyl azide and a radical initiator. Enantiomerically enriched azides were thus obtained in yields of 59–81 % and enantioselectivities of up to 94:6 e.r. (98:2 e.r. if the intermediate dialkylborane is purified by crystallization). A rapid access to enantiomerically pure (+)-rodocaine is also described. The use of other arenesulfonyl radical traps enables enantioselective hydroallylation, hydrosulfanylation, and hydrobromination reactions with yields of 71–86 %.
An efficient method for chlorination of alcohols using PPh3/Cl3CCONH2
Pluempanupat, Wanchai,Chavasiri, Warinthorn
, p. 6821 - 6823 (2007/10/03)
A new and convenient method for the chlorination of alcohols utilizing PPh3/Cl3CCONH2 is addressed. Various alcohols could smoothly be converted into their corresponding alkyl chlorides in high yield under mild conditions with short reaction times. A mechanism is disclosed with the evidence of inversion of configuration of the analogous alkyl chloride derived from R-(-)-2-octanol.
Stereospecific Substituted Alkene Synthesis by Organo Lithium Reductive Alkylation of Epoxides
Doris, Eric,Dechoux, Luc,Mioskowski, Charles
, p. 7943 - 7946 (2007/10/02)
Stereospecifically alkylated olefins were synthesized in good yields by reaction of various epoxides with organolithium reagents with concommitant introduction of the alkyl group.
