34295-85-7

Basic information

• Product Name: salicylidene-beta-alanine
• Synonyms: salicylidene-beta-alanine
• CAS NO: 34295-85-7
• Molecular Formula: C₁₀H₁₁NO₃
• Molecular Weight: 0
• Mol File: 34295-85-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 415.8°Cat760mmHg
• Flash Point: 205.3°C
• Appearance: /
• Density: 1.349g/cm³
• Vapor Pressure: 4.45E-08mmHg at 25°C
• Refractive Index: 1.651
• CAS DataBase Reference: salicylidene-beta-alanine(CAS DataBase Reference)
• NIST Chemistry Reference: salicylidene-beta-alanine(34295-85-7)
• EPA Substance Registry System: salicylidene-beta-alanine(34295-85-7)

Safety Data

• Hazardous Substances Data: 34295-85-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H11NO3/c12-9-4-2-1-3-8(9)7-11-6-5-10(13)14/h1-4,7,11H,5-6H2,(H,13,14)/b8-7+

Upstream product

• 90-02-8 salicylaldehyde 
• 107-95-9 3-amino propanoic acid 

Downstream Products

• 162127-00-6 N-(2-hydroxybenzyl)-3-aminopropanoic acid 
• 90-02-8 salicylaldehyde 
• 107-95-9 3-amino propanoic acid 
• 53058-96-1 Ce⁽³⁺⁾*C₁₀H₉NO₃^(2-)*C₁₀H₁₀NO₃^(1-)=Ce(C₁₀H₉NO₃)(C₁₀H₁₀NO₃) 
• 53041-90-0 Nd⁽³⁺⁾*C₁₀H₉NO₃^(2-)*C₁₀H₁₀NO₃^(1-)=Nd(C₁₀H₉NO₃)(C₁₀H₁₀NO₃) 
• 53041-91-1 Sm⁽³⁺⁾*C₁₀H₉NO₃^(2-)*C₁₀H₁₀NO₃^(1-)=Sm(C₁₀H₉NO₃)(C₁₀H₁₀NO₃) 
• 53058-95-0 La⁽³⁺⁾*C₁₀H₉NO₃^(2-)*C₁₀H₁₀NO₃^(1-)=La(C₁₀H₉NO₃)(C₁₀H₁₀NO₃) 
• 53058-97-2 Pr⁽³⁺⁾*C₁₀H₉NO₃^(2-)*C₁₀H₁₀NO₃^(1-)=Pr(C₁₀H₉NO₃)(C₁₀H₁₀NO₃) 

Relevant articles and documents

Tridentate Schiff base coordinated trigonal bipyramidal / square pyramidal copper(II) complexes: Synthesis, crystal structure, DFT / TD-DFT calculation, catecholase activity and DNA binding

Using tridentate O,N,O/N,N,O donor Schiff bases and 1,10-phenanthroline, five coordinated copper(II) complexes, {[Cu(L1)(phen)][Cu(L1)(phen)]?5H2O}(1) and {[Cu(L2)(phen)](ClO4)}(2) [H2Lsup

Heterovalent trinuclear Co(III)-Co(II)-Co(III) complexes with N-(2-carboxyethyl)salicylaldimines

He heterovalent trinuclear cobalt complexes [Co2 IIIL4i · CoII(H 2O)4] · nXmY (Li are deprotonated Schiff bases derived from substituted salicylaldehydes and β-alanine; i = 1-3) were obtained and characterized. An X-ray diffraction study of the trinuclear cobalt complex with N-(2-carboxyethyl)salicylaldimine showed that the central Co(II) ion and the terminal Co(III) ions are linked by bridging carboxylate groups. Either terminal Co(III) atom is coordinated to two ligand molecules. They form an octahedral environment consisting of two azomethine N atoms, two phenolate O atoms, and two O atoms of two carboxylate groups. The central Co(II) atom is coordinated to four water molecules and to two O atoms of two bridging carboxylate ligands involved in the coordination sphere of the terminal Co(III) atoms. Pleiades Publishing, Ltd., 2012.

Structure-stability correlations for imine formation in aqueous solution

Imine formation between 25 aldehydes and 13 amines in aqueous solution in the pH range 7-11 was studied by 1H NMR spectroscopy. A three-parameter linear equation correlating logarithms of imine formation constants with pKa and HOMO energies of amines and LUMO energies of aldehydes is proposed. In view of the widespread occurrence of imine-forming processes in both chemistry and biology, the data presented are of significance for physical organic chemistry and of particular interest for dynamic combinatorial chemistry. Copyright