344349-72-0

Basic information

• Product Name: Benzoic acid 4-hydroxy-4-methyl-cyclohexyl ester
• Synonyms: Benzoic acid 4-hydroxy-4-methyl-cyclohexyl ester
• CAS NO: 344349-72-0
• Molecular Weight: 234.295
• Mol File: 344349-72-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid 4-hydroxy-4-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid 4-hydroxy-4-methyl-cyclohexyl ester(344349-72-0)
• EPA Substance Registry System: Benzoic acid 4-hydroxy-4-methyl-cyclohexyl ester(344349-72-0)

Safety Data

• Hazardous Substances Data: 344349-72-0(Hazardous Substances Data)

Upstream product

• 89794-52-5 1-methyl-1,4-cyclohexanediol 
• 98-88-4 benzoyl chloride 
• 17429-02-6 4-hydroxy-4-methylcyclohexanone 
• 66336-42-3 8-methyl-1,4-dioxa-spiro[4.5]decan-8-ol 
• 4746-97-8 cyclohexanedione monoethylene ketal 

Relevant articles and documents

A unified photoredox-catalysis strategy for C(sp3)-H hydroxylation and amidation using hypervalent iodine

We report a unified photoredox-catalysis strategy for both hydroxylation and amidation of tertiary and benzylic C-H bonds. Use of hydroxyl perfluorobenziodoxole (PFBl-OH) oxidant is critical for efficient tertiary C-H functionalization, likely due to the enhanced electrophilicity of the benziodoxole radical. Benzylic methylene C-H bonds can be hydroxylated or amidated using unmodified hydroxyl benziodoxole oxidant Bl-OH under similar conditions. An ionic mechanism involving nucleophilic trapping of a carbocation intermediate by H2O or CH3CN cosolvent is presented.