344350-86-3

Basic information

• Product Name: 2-(Benzoyloxy)-<3,3-D2>-2-azabicyclo<2.2.1>heptan
• CAS NO: 344350-86-3
• Molecular Weight: 219.252
• Mol File: 344350-86-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(Benzoyloxy)-<3,3-D2>-2-azabicyclo<2.2.1>heptan(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Benzoyloxy)-<3,3-D2>-2-azabicyclo<2.2.1>heptan(344350-86-3)
• EPA Substance Registry System: 2-(Benzoyloxy)-<3,3-D2>-2-azabicyclo<2.2.1>heptan(344350-86-3)

Safety Data

• Hazardous Substances Data: 344350-86-3(Hazardous Substances Data)

Upstream product

• 49805-30-3 2-azabicyclo[2.2.1.]hept-5-en-3-one 
• 542-92-7 cyclopenta-1,3-diene 
• 24647-29-8 2-Azabicyclo[2.2.1]heptan-3-one 
• 344244-01-5 <3,3-D2>-2-Azabicyclo<2.2.1>heptan 
• 94-36-0 dibenzoyl peroxide 

Relevant articles and documents

Nitrenium and Carbenium Ions in Rearrangements of 2-Azabicyclic Systems

An ionic mechanism proceeding in intimate ion pairs is suggested for the rearrangement of N-sulfonyloxy derivatives of 2-azabicycloheptane and -hept-5-ene (e. g. 9, 11 -> 10, 12). 1.Experiments with 18O labelled educts show partial scrambling dependend both on structure of educt and solvent. 2.In methanol the intermediate carbenium ions (19, 23) react to give methoxy compounds. 3.MINDO/3-calculations are in agreement with the experiments: a) In the saturated systems the nitrenium ion 20 is a stable intermediate. b) The optimized geometries of the rearranged carbenium ions (21, 23) are consistent with the products obtained in methanol.