344614-17-1

Basic information

• Product Name: W(η2-2-mercaptopyridine)4
• CAS NO: 344614-17-1
• Molecular Weight: 624.488
• Mol File: 344614-17-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: W(η2-2-mercaptopyridine)4(CAS DataBase Reference)
• NIST Chemistry Reference: W(η2-2-mercaptopyridine)4(344614-17-1)
• EPA Substance Registry System: W(η2-2-mercaptopyridine)4(344614-17-1)

Safety Data

• Hazardous Substances Data: 344614-17-1(Hazardous Substances Data)

Upstream product

• 2637-34-5 2-Sulfanylpyridine 
• 16800-47-8 tricarbonyl-tris(acetonitrile)tungsten⁽⁰⁾ 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Synthesis and characterization of 6,7 and 8-coordinate monomeric complexes of tungsten obtained from reaction of [W(CO)3(MeCN)3] with pyridine-2-thiol (pySH) and PPh3

Complexes [W(CO)4(PPh3)2] 1, [W(CO) 4(pySH)(PPh3)] 2, [W(CO)2(pyS) 2(PPh3)] 3 and [W(pyS)4] 4 have been obtained from the reaction of [W(CO)3(MeCN)3] with pyridine-2-thiol (pySH) and PPh3 in refluxing THF. 1 and 2 are normal 6-coordinate complexes but 3 and 4 are unusual 7 and 8-coordinate complexes, respectively. The complexes have been characterized by IR, 1H and 31P{1H}NMR, mass spectra and elemental analysis.