34495-73-3

Basic information

• Product Name: ethyl cis-4-hexenoate
• Synonyms: ethyl cis-4-hexenoate
• CAS NO: 34495-73-3
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 142.19556
• Mol File: 34495-73-3.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ethyl cis-4-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl cis-4-hexenoate(34495-73-3)
• EPA Substance Registry System: ethyl cis-4-hexenoate(34495-73-3)

Safety Data

• Hazardous Substances Data: 34495-73-3(Hazardous Substances Data)

Upstream product

• 590-18-1 (Z)-2-Butene 
• 20363-85-3 diethyl mercuribis(diazoacetate) 
• 590-13-6 (Z)-1-propenyl bromide 
• 140-88-5 ethyl acrylate 
• 84200-40-8 (Z)-diethyl (but-2-en-1-yl)malonate 
• 50479-11-3 (3-ethoxycarbonylpropyl)triphenylphosphonium bromide 
• 75-07-0 acetaldehyde 
• 598-32-3 2-hydroxy-3-butene 
• 78-39-7 Triethyl orthoacetate 
• 2969-81-5 Ethyl 4-bromobutyrate 

Downstream Products

• 928-91-6 (Z)-4-hexenol 
• 4634-89-3 cis-hex-4-enal 

Relevant articles and documents

TOTAL STEREOSPECIFICITY IN FREE RADICAL INTRAMOLECULAR ADDITION: CYCLISATION OF CIS AND TRANS 1-METHYL 4-HEXENYL N-CHLOROAMINES BY MEANS OF METALLIC SALTS

Extremely high stereospecificity (up to 100percent diastereoisomeric purity) can be obtained for the metallic salts induced radical cyclisation of the cis and trans 1-methyl 4-hexenyl N-chloroamines.A possible mechanism for the highly effective trans-addition using metal-complexed aminyl radical is proposed.

REACTIONS OF ORGANIC HALIDES WITH OLEFINS UNDER Ni0-CATALYSIS. FORMAL ADDITION OF HYDROCARBONS TO CC-DOUBLE BONDS

The reaction of various types of organic halides with electron deficient olefins under the influence of NiCl2 x 6 H2O in the presence of zinc and pyridine leads to formal addition products of hydrocarbons to CC-double bonds in good yield.