34495-74-4Relevant articles and documents
(BDP)CuH: A "hot" Stryker's reagent for use in achiral conjugate reductions
Baker, Benjamin A.,Boskovic, Zarko V.,Lipshutz, Bruce H.
, p. 289 - 292 (2008/09/19)
(Chemical Equation Presented) A ligand-modified, economical version of Stryker's reagent (SR) has been developed based on a bidentate, achiral bis-phosphine. Generated in situ, "(BDP)CuH" smoothly effects conjugate reductions of a variety of unsaturated substrates, including those that are normally unreactive toward SR. Substrate-to-ligand ratios typically on the order of 1000-10000:1 can be used leading to products in high yields.
NICKEL CATALYZED COUPLING OF ACTIVATED ALKENES WITH ORGANIC HALIDES
Boldrini, G. P.,Savoia, D.,Tagliavini, E.,Trombini, C.,Ronchi, A. Umani
, p. C62 - C64 (2007/10/02)
Alkenenickel complexes catalyze the coupling of activated olefins with aryl or vinyl halides.Substitution or conjugate-addition products are obtained depending on the activating group in the alkene and on the nature of the organic halide.
