345292-85-5Relevant articles and documents
CYCLIC TRIMERIZATION OF ACETYLENES TO FULVENES
Chukhadzhyan, G. A.,Abramyan, Zh. I.,Tonyan, G. M.,Sagradyan, L. I.,Elbakyan, T. S.
, p. 1636 - 1640 (2007/10/02)
The catalytic transformation of acetylene and its derivatives at palladium complexes was investigated.Acetylene, phenylacetylene, and tert-butylacetylene are converted into the fulvene valence isomers of benzene in the presence of cationic bisarene complexes of palladium Pd(AlCl4)2*2C6H6 and Pd(Al3Cl7)2*2C6H6 and also in the presence of Pd(OAc)2 and Pd.