345305-22-8Relevant articles and documents
Catalytic asymmetric hydroboration of heterofunctional allylic substrates: an efficient heterogenized version
Lillo, Vanesa,Fernandez, Elena,Segarra, Anna M.
, p. 911 - 914 (2007)
The hydroboration of heterofunctional allylic systems with catecholborane (HBcat) using neutral and cationic rhodium complexes modified with P-P and P-N bidentate chiral ligands has been described in order to produce the secondary heteroorganoboronate ester as a major product with moderate enantioselectivity. The immobilization of cationic chiral rhodium complexes onto clays has beneficial effects on the recyclability and reuse of the catalytic system in particular for the hydroboration of allyl aryl sulfones.
Lipase-catalyzed kinetic resolution of 3-phenyloxazolidin-2-one derivatives: Cascade O- and N-alkoxycarbonylations
Zhang, Yang,Zhang, Yan,Xie, Sheng,Yan, Mingdi,Ramstr?m, Olof
, p. 11 - 15 (2016/05/09)
A lipase-catalyzed, cascade kinetic resolution protocol has been established for the synthesis of 3-phenyloxazolidin-2-one derivatives with up to excellent enantioselectivities (95% ee). Candida antarctica lipase B showed high catalytic activity and stere
A new recyclable functionalized mesoporous SBA-15 catalyst grafted with chiral Fe(iii) sites for the enantioselective aminolysis of racemic epoxides under solvent free conditions
Halder, Mita,Bhanja, Piyali,Roy, Susmita,Ghosh, Swarbhanu,Kundu, Sudipta,Islam, Md. Mominul,Islam, Sk. Manirul
, p. 97599 - 97605 (2016/10/31)
An efficient and enantioselective strategy for the catalytic ring opening of racemic meso and terminal epoxides with aromatic as well as cyclic amine derivatives has been reported over a new mesoporous SBA-15 catalyst grafted with a chiral Fe(iii) complex