34557-72-7

Basic information

• Product Name: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride
• CAS NO: 34557-72-7
• Molecular Weight: 703.124
• Mol File: 34557-72-7.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride(34557-72-7)
• EPA Substance Registry System: 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride(34557-72-7)

Safety Data

• Hazardous Substances Data: 34557-72-7(Hazardous Substances Data)

Upstream product

• 54438-78-7 (tetraphenylporphyrin)(nitrosyl)MnCl 
• 917-23-7 5,10,15,20-tetraphenyl-21H,23H-porphine 
• 7773-01-5 manganese(ll) chloride 
• 83632-54-6 nitridomanganese(V) meso-tetraphenylporphyrinate 
• 917-23-7 5,15,10,20-tetraphenylporphyrin 
• 58356-65-3 [MnIII(TPP)(OAc)] 
• 89789-33-3 tetraphenylporphinatomanganese(III) fluoride 
• 7647-14-5 sodium chloride 
• 56413-47-9 azidomanganese(III) meso-tetraphenylporphyrin 
• 90-13-1 1-Chloronaphthalene 
• 638-38-0 manganese(II) acetate 
• 14977-07-2 5,10,15,20-tetraphenylporphyrinato cadmium(II) 
• 58356-65-3 manganese(III) meso-tetraphenylporphyrin acetate 
• 1112-67-0 tetrabutyl-ammonium chloride 

Downstream Products

• 31004-82-7 manganese(II) 5,10,15,20-tetraphenylporphyrinate 
• 71155-87-8 manganese(III)tetraphenylporphine(pyridine)⁽¹⁺⁾ 
• 76077-77-5 ClMn(IV)(O)(tetraphenylporphyrin) 
• 83632-54-6 nitridomanganese(V) meso-tetraphenylporphyrinate 
• 58356-65-3 manganese(III) meso-tetraphenylporphyrin acetate 
• 55290-32-9 bromo(5,10,15,20-tetraphenylporphyrinato)manganese(III) 
• 105121-85-5 Mn(C₆H₅C₅H₂N)4(CF₃SO₃) 
• 83160-29-6 (dimethylsulfato-κO)(5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN(21),κN(22),κN(23),κN(24))manganese(II) 
• 57034-31-8 manganese(II)tetraphenylporphine(pyridine) 
• 54438-78-7 (tetraphenylporphyrin)(nitrosyl)MnCl 
• 76077-77-5 {Mn(O)(tetraphenylporphyrin^(2-))} 
• 210409-38-4 tetrabutylammonium dicyano(meso-tetraphenylporphyrinato)manganate(III) 
• 79408-54-1 (tetraphenylporphyrinato)manganese(III) perchlorate 
• 67161-73-3 5,10,15,20-tetraphenylporphyrin-manganese(III) perchlorate 

Relevant articles and documents

Linkage Isomers of 4-Methylimidazolate Mn(II) Porphyrinates: Hindered or Unhindered?

Three different manganese(II) porphyrins have been exploited to react with 4-methylimidazolate (4-MeIm-), and the five-coordinate products are characterized by ultraviolet-visible, single-crystal X-ray, and electronic paramagnetic resonance spectroscopies. Interestingly, 4-MeIm- is found to bond to the metal center through either of the two N atoms (N1 or N3), which yielded two linkage isomers with either an unhindered or a hindered ligand conformation, respectively. Investigations revealed it is the large metal out-of-plane displacements (Δ24 and Δ4 ≥ 0.59 ?) that have rendered the equivalence of two isomers with a small energy difference (5.2-8.3 kJ/mol). The nonbonded intra- and intermolecular interactions thus become crucial factors in the balance of linkage isomerization. All of the products in both solution and solid states show the same characteristic resonances of high-spin Mn(II) (S = 5/2) with g⊥ ≈ 5.9 and g⊥ ≈ 2.0 at 4 K, consistent with the weak effects of the axial ligand on core conformation and metal electronic configurations. Zero-field splitting parameters obtained through simulations are also reported.

Method for synthesizing tetraaryl manganese porphyrin through synchronous aldehyde and pyrrole condensation and bivalent manganese salt oxidation insertion reaction

The invention discloses a method for synthesizing tetraaryl manganese porphyrin by synchronous aldehyde and pyrrole condensation and bivalent manganese salt oxidation insertion reaction. Aromatic aldehyde, pyrrole and manganese dichloride are refluxed in

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Studying the axial ligation behavior of metalloporphyrins with nitrogenous bases helps to better understand not only the biological function of heme-based protein systems, but also the catalytic properties of porphyrin-based reaction sites in other biomim