3462-50-8Relevant articles and documents
λ3-Iodanes as Visible Light Photocatalyst in Thioacetalization of Aldehydes
Choudhuri, Khokan,Pramanik, Milan,Mal, Prasenjit
supporting information, p. 4822 - 4826 (2019/07/31)
Introduction of an iodine(III) reagent as visible-light photocatalyst for chemoselective dithioacetalization has been the limelight of the current methodology. The mechanistic investigations reveal that the reactions proceeded via radical pathway upon lig
Highly regioselective double hydrothiolation of terminal acetylenes with thiols catalyzed by palladium diacetate
Mitamura, Takenori,Daitou, Masayuki,Nomoto, Akihiro,Ogawa, Akiya
, p. 413 - 415 (2011/05/16)
Treatment of terminal acetylenes 1 with two equivalents of thiols 2 in the presence of Pd(OAc)2 catalyst and H2O causes regioselective double hydrothiolation of 1, leading to the corresponding dithioketals 3 in moderate to good yields.
Green, catalyst-free thioacetalization of carbonyl compounds using glycerol as recyclable solvent
Perin, Gelson,Mello, Luzia G.,Radatz, Cátia S.,Savegnago, Lucielli,Alves, Diego,Jacob, Raquel G.,Lenard?o, Eder J.
experimental part, p. 4354 - 4356 (2010/09/12)
We describe herein the use of glycerol as an efficient and a recyclable solvent in the thioacetalization of aldehydes and ketones. The catalyst-free reactions proceed easily using glycerol at 90 °C and the corresponding thioacetals were obtained in good to excellent yields. Glycerol was recovered and utilized for further thioacetalization reactions.