34640-76-1

Basic information

• Product Name: bicyclo[2.2.1]hept-2-yl acetate
• Synonyms: Norbornyl acetate;2-NORBORNYL ACETATE;bicyclo[2.2.1]hept-2-yl acetate;Acetic acid bicyclo[2.2.1]heptane-2-yl ester;Acetic acid norbornane-2-yl ester;Bicyclo[2.2.1]heptan-2-ol acetate
• CAS NO: 34640-76-1
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.20626
• EINECS: 252-123-6
• Mol File: 34640-76-1.mol
• Article Data: 30

Chemical Properties

• Boiling Point: 201°Cat760mmHg
• Flash Point: 69°C
• Appearance: /
• Density: 1.06g/cm³
• Vapor Pressure: 0.315mmHg at 25°C
• Refractive Index: 1.482
• CAS DataBase Reference: bicyclo[2.2.1]hept-2-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclo[2.2.1]hept-2-yl acetate(34640-76-1)
• EPA Substance Registry System: bicyclo[2.2.1]hept-2-yl acetate(34640-76-1)

Safety Data

• Hazardous Substances Data: 34640-76-1(Hazardous Substances Data)

Usage

General Description

Bicyclo[2.2.1]hept-2-yl acetate, also known as norbornane acetate, is a chemical compound with a bicyclic structure that contains a seven-membered ring. It is commonly used as a fragrance ingredient in various consumer products, such as perfumes, soaps, and air fresheners, due to its pleasant odor. Bicyclo[2.2.1]hept-2-yl acetate has a fruity, floral, and slightly spicy aroma, making it a popular choice for adding a sweet and refreshing scent to personal care and household items. It is also used in the manufacture of flavors and fragrances, as well as in the synthesis of other organic compounds. This chemical compound is generally considered safe for use in consumer products when used in accordance with regulatory guidelines.

InChI:InChI=1/C9H14O2/c1-6(10)11-9-5-7-2-3-8(9)4-7/h7-9H,2-5H2,1H3

Upstream product

• 100-42-5 styrene 
• 80484-23-7 2-Acetoxy-2-norbornylquecksilberchlorid 
• 498-66-8 norborn-2-ene 
• 546-67-8 lead(IV) tetraacetate 
• 4786-20-3 crotononitrile 
• 75-35-4 1,1-Dichloroethylene 
• 591-09-3 nitro acetate 
• 29342-65-2 2-bromonorbornane 
• 10395-53-6 2-methoxybicyclo[2.2.1]heptane 
• 2890-95-1 5-acetoxynorborn-2-ene 
• 840-88-0 exo-2-norbornyl p-bromobenzenesulfonate 
• 64-19-7 acetic acid 
• 840-89-1 endo-norbornyl brosylate 
• 107-13-1 acrylonitrile 

Downstream Products

• 497-36-9 (+/-)-endo-2-norborneol 
• 497-36-9 endo-norborneol 
• 61277-90-5 exo-norborneol 
• 497-37-0 exo-2-norbornanol 
• 497-38-1 Norbornan-2-on 
• 61242-45-3 (+/-)-phthalic acid mono-[2endo]norbornyl ester 
• 100871-13-4 (+/-)-3,5-dinitro-benzoic acid-[2endo]norbornyl ester 
• 29753-02-4 norbornyl (meth)acrylate 
• 10027-06-2 norbornyl acrylate 
• 497-36-9 Norborneol 

Relevant articles and documents

Ionization of 2-Brexyl Brosylate: An Exo-Like Rate without Symmetrical Bridging

2-Brexyl brosylate and exo-norbornyl brosylate show similar ionization rates but differ markedly with respect to internal return, secondary isotope effect, and optical activity

Consecutive addition esterification and hydrolysis of cyclic olefins catalyzed by multi-SO3H functionalized multi heteropolyanion-based ionic hybrids undersolvent-free conditions

An efficient protocol for the synthesis of cycloalkyl carboxylates and alcohols from cyclic olefins is described. The cyclic olefins were converted to corresponding target molecules under solvent-free conditions catalyzed by two novel multi-SO3H functionalized multi heteropolyanion-based ionic hybrids through one-pot consecutive addition esterification and hydrolysis reactions. This approach has several advantages, including high yield, simple workup and simple purification.

Addition of alcohols and acids to olefins in presence of zeolite catalyst H-beta

By studying the reactions of styrene and norbornene with different alcohols and carbonic acids in the presence of heterogenic catalyst, it was found that the selected zeolite H-Beta is an active and selective catalyst for these reactions. Ethers and esters of norbornene have exo-configuration. It has been established that reaction of norbornene with diols, catalyzing by zeolite Beta, leads to the formation of esters, which have not been found before.

Stereoselective exo-addition to norbornenes of acetic acid generated from vinyl acetate in the presence of rhodium complexes

Rhodium complexes catalyzed decomposition of vinyl acetate with liberation of acetic acid and subsequent stereoselective exo-addition of the latter to norbornene and its derivatives under mild conditions.