34680-56-3Relevant articles and documents
Three Component Reactions. XII. Alkoxychlorination of 3-Chloropropene and 3-Methoxypropene
Beger, J.,Schiefer, H.
, p. 1039 - 1047 (2007/10/02)
By capillar GLC and 13C-n.m.r. spectroscopy was demonstrated, that - in contrast to the communications of other authors - both expected isomeric alkoxychlorination products are formed in the chlorination of 3-chloropropene in presence of several alkanols.Isomers with anti-Markovnikov orientation dominated in all pairs of isomers which we have identified.Analogous product relations were found in the chlorination as well as in the methoxychlorination of 3-methoxypropene.