34736-50-0Relevant articles and documents
Facile preparation of silyl azides with dipolar aprotic solvents
S. Washburne, Stephen,R. Peterson Jr., William
, p. 153 - 156 (1971)
The reaction of sodium azide with chlorosilanes in hexamethylphosphoric triamide or dimethylformamide at room temperature affords a high yield preparation of silyl azides, e.g. Me3SiN3,Me2Si(N3)2, PhMeSi(N3)2 and Ph2Si(N3)2. For characterization, the azides may be converted to silyphosphiimies, R3Si-N=PPh3.