34875-71-3Relevant articles and documents
BuLi-triggered phospha-Brook rearrangement: Efficient synthesis of organophosphates from ketones and aldehydes
Pallikonda, Gangaram,Santosh, Ranga,Ghosal, Subhas,Chakravarty, Manab
, p. 3796 - 3798 (2015/06/08)
A variety of organophosphates are synthesized from n-BuLi-triggered, (additional) solvent-free reactions of diethyl phosphite with both activated/unactivated ketones and aldehydes preferably at room temperature via phospha-Brook rearrangement. We could successfully synthesize the naphthylic/allylic phosphates using this approach.