34896-15-6Relevant articles and documents
Direct oxidation of the C(sp2)-C(sp3) bond from benzyltrimethylsilanes to phenols
Li, Wei,Gao, Guolin,Gao, Yuan,Yang, Chao,Xia, Wujiong
, p. 5291 - 5293 (2017)
A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na2S2O8 and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.
THE REACTION OF ALKYL PHOSPHITES WITH 3,5-DI-TERT-BUTYL-1,2-BENZOQUINONE. VARIABLE TEMPERATURE NMR STUDIES ON NEW PENTAOXYPHOSPHORANES
Abdou, Wafaa M.,Mahran, Mohamed Refat H.,Hafez, Taghrid S.,Sidky, Mahmoud M.
, p. 345 - 354 (2007/10/02)
3,5-Di-tert-butyl-1,2-benzoquinone (5) reacts with trialkyl phosphites (6) to give the respective pentaoxyphosphoranes 7.On the other hand, the reaction of quinone 5 with dialkyl phosphites affords the phosphonate adducts 13.Analytical and spectroscopic (