34918-74-6

Basic information

• Product Name: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-
• CAS NO: 34918-74-6
• Molecular Formula: C14H12ClNO
• Molecular Weight: 245.708
• Mol File: 34918-74-6.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-(34918-74-6)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, N-(4-methoxyphenyl)-(34918-74-6)

Safety Data

• Hazardous Substances Data: 34918-74-6(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 98-88-4 benzoyl chloride 
• 7472-54-0 N-(p-methoxyphenyl)benzamide 

Downstream Products

• 1281681-02-4 3-(N-4-methoxyphenylbenzimidoyl)-1-(3-pyridylmethyl)thiourea 
• 1281681-04-6 1-ethoxycarbonylmethyl-3-(N-4-methoxyphenylbenzymidoyl)thiourea 
• 38706-65-9 C₂₁H₂₁N₃O 
• 38259-63-1 N-(4-methoxy-2-nitrophenyl)benzamide 
• 98888-78-9 (4-Methoxy-phenyl)-thiobenzoyl-thiocarbamic acid O-ethyl ester 
• 98888-77-8 (4-Methoxy-phenyl)-thiobenzoyl-thiocarbamic acid O-methyl ester 
• 73333-81-0 N-(4-methoxyphenyl)-N-phenylbenzamide 
• 59484-13-8 phenyl N-(4-methoxyphenyl)benzimidate 
• 1609460-37-8 N-benzyl-N′-(4-methoxyphenyl)benzimidamide 
• 1315314-52-3 6-methoxy-2,4-diphenylquinazoline 

Relevant articles and documents

Synthesis of N-Hydroxy-N-(o-chlorophenyl)-N'-(p-methoxyphenyl)benzamidine Hydrochloride and Its Reactions with Various Metal Ions

A new reagent N-hydroxy-N-(o-chlorophenyl)-N'-(p-methoxyphenyl)benzamidine hydrochloride, has been synthesized and is characterized on the basis of mp, elemental analysis, IR and UV spectra.The reactions of the reagent with metal ions suggest that new met

α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles

Imidoyl sulfoxonium ylides are presented for the first time as potential precursors to generate α-imino metal-carbene intermediates and applied in direct C-H functionalization reactions catalyzed by [Ir(cod)Cl]2 (4 mol %) to provide 2-substituted indoles (up to 70% yield) in just one step. This class of sulfur ylide is successfully obtained from imidoyl chloride and dimethylsulfoxonium methylide (23 new examples in 45-85% yield) or by imino group formation from the corresponding β-keto sulfoxonium ylides and anilines in the presence of TiCl4 as a Lewis acid (9 examples in 33-94% yield).

Synthesis of Nitrogen-Containing Polyaromatics by Aza-Annulative π-Extension of Unfunctionalized Aromatics

Nitrogen-containing polycyclic aromatic compounds (N-PACs) are an important class of compounds in materials science. Reported here is a new aza-annulative π-extension (aza-APEX) reaction that allows rapid access to a range of N-PACs in 11–84 % yields from readily available unfunctionalized aromatics and imidoyl chlorides. In the presence of silver hexafluorophosphate, arenes and imidoyl chlorides couple in a regioselective fashion. The follow-up oxidative treatment with p-chloranil affords structurally diverse N-PACs, which are very difficult to synthesize. DFT calculations reveal that the aza-APEX reaction proceeds through the formal [4+2] cycloaddition of an arene and an in situ generated diarylnitrilium salt, with sequential aromatizations having relatively low activation energies. Transformation of N-PACs into nitrogen-doped nanographenes and their photophysical properties are also described.