34930-11-5

Basic information

• Product Name: S-(4-methylbenzyl)dithiocarbazate
• Synonyms: S-(4-methylbenzyl)dithiocarbazate
• CAS NO: 34930-11-5
• Molecular Weight: 212.34
• Mol File: 34930-11-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: S-(4-methylbenzyl)dithiocarbazate(CAS DataBase Reference)
• NIST Chemistry Reference: S-(4-methylbenzyl)dithiocarbazate(34930-11-5)
• EPA Substance Registry System: S-(4-methylbenzyl)dithiocarbazate(34930-11-5)

Safety Data

• Hazardous Substances Data: 34930-11-5(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 104-82-5 4-Methylbenzyl chloride 
• 471-32-9 dithiocarbonic acid hydrazide 

Downstream Products

• 1599471-49-4 C₁₇H₁₉N₃S₂ 
• 1599471-55-2 C₂₄H₂₂CuN₄O₃S₃ 
• 401641-23-4 2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole 
• 34930-34-2 5-(4-methyl-benzylsulfanyl)-[1,2,3,4]thiatriazole 

Relevant articles and documents

Synthesis, characterization and biological studies of S-4-methylbenzyl-β-N-(2-furylmethylene)dithiocarbazate (S4MFuH) its Zn2+, Cu2+, Cd2+ and Ni2+ complexes

S-4-methylbenzyl-β-N-(2-furylmethylene)dithiocarbazate (S4MFuH, 1) derived from the condensation reaction of furaldehyde (Fu) with S-4-methylbenzyldithiocarbazate (S4MBDTC) has been complexed with transition metal acetates to give Zn(S4MFu)2 (2

Synthesis, characterisation and biological activities of S-2- or S-4-methylbenzyl-β-N-(di-2-pyridyl)methylenedithiocarbazate and Cu(II), Ni(II), Zn(II) and Cd(II) complexes

Metal complexes of general formula, [M(NNS)2] (M?=?Cu(II), Ni(II), Zn(II) and Cd(II); NNS′?=?S-2-methylbenzyl-β-N-(di-2-pyridyl)methylenedithiocarbazate (1), NNS″?=?S-3-methylbenzyl-β-N-(di-2-pyridyl)methylenedithiocarbazate (2) and NNS??=?S-4-

Isolation, characterization and X-ray structure determination of 2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole

The reaction of hydrazine hydrate with carbon disulfide and 4-methylbenzyl chloride in basic solution yielded 2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole (C18H18N2S3, compound 1) in addition to the expected S-4-methylbenzyldithiocarbazate. The molecule has approximate twofold symmetry with the C=S bond lying on the pseudo axis. The five membered ring is planar with the three S atoms mutually syn, and with pendent 4-methylbenzylthio substituents; the dihedral angle between the terminal rings is 52.21(7). The compound 1 crystallizes in the triclinic space group P 1 with a = 6.0139(3) A, b = 11.8694(7) A, c = 12.6330(7) A, α = 72.583(5), β = 82.827(4), γ = 89.882(4) and Z = 2. Graphical Abstract: In situ cyclization of an authenticated dithiocarbazate gave rise to a supramolecular layerered assembly of new molecules containing a 1,3,4-thiadiazole ring system having a strictly planar central core with mutually syn sulfur atoms and terminal aryl groups twisted out of this plane.[Figure not available: see fulltext.]