34940-01-7

Basic information

• Product Name: (R)-3-methyl-3-phenylpentan-2-one
• Synonyms: (R)-3-methyl-3-phenylpentan-2-one
• CAS NO: 34940-01-7
• Molecular Weight: 176.258
• Mol File: 34940-01-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-3-methyl-3-phenylpentan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-methyl-3-phenylpentan-2-one(34940-01-7)
• EPA Substance Registry System: (R)-3-methyl-3-phenylpentan-2-one(34940-01-7)

Safety Data

• Hazardous Substances Data: 34940-01-7(Hazardous Substances Data)

Upstream product

• 1201898-74-9 (S)-4,4,5,5-tetramethyl-2-(2-phenylbutan-2-yl)-1,3,2-dioxaborolane 
• 109-92-2 ethyl vinyl ether 
• 506-82-1 dimethylcadmium 
• 157750-19-1 (-)-(2R)-2-Methyl-2-phenylbutanoyl chloride 
• 3968-79-4 (R)-2-methyl-2-phenylbutanamide 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 32737-70-5 (3R,4R)-3,4-dimethyl-4-phenyl-hexan-3-ol 

Relevant articles and documents

Enantioselective construction of quaternary stereogenic centers from tertiary boronic esters: Methodology and applications

Pin it down: A range of substrates that bear versatile functional groups with quaternary stereogenic centers have been prepared with very high enantioselectivity from tertiary boronic esters (see scheme; Cb=N,N-diisopropylcarbamoyl, pin=pinacolato). The preparation of allylboronic esters bearing contiguous quaternary and tertiary stereogenic centers, and applications to natural product synthesis are also reported.