349616-56-4

Basic information

• Product Name: [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane
• Synonyms: [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane;Tributyl[5-(1,3-dioxolan-2-yl)-2-thienyl]stannane
• CAS NO: 349616-56-4
• Molecular Formula: C₁₉H₃₄O₂SSn
• Molecular Weight: 445.24706
• Mol File: 349616-56-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 452.1±55.0 °C(Predicted)
• Appearance: /
• CAS DataBase Reference: [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane(CAS DataBase Reference)
• NIST Chemistry Reference: [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane(349616-56-4)
• EPA Substance Registry System: [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane(349616-56-4)

Safety Data

• Hazardous Substances Data: 349616-56-4(Hazardous Substances Data)

Usage

Description

[5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane is a stannane compound characterized by the presence of a tributylstannane group attached to a thiophen-2-yl ring with a dioxolan-2-yl substituent. This organotin compound is predominantly utilized in the field of organic synthesis, where it serves as a valuable reagent or catalyst. The unique structural composition of this compound, which includes thiophene and dioxolane moieties, suggests its potential use in a variety of organic chemistry reactions. However, it is also important to be aware of the possible toxicological and environmental implications associated with the use of organotin compounds, and to handle and utilize this chemical with appropriate caution.

Uses

Used in Organic Synthesis:
[5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane is used as a reagent in the field of organic synthesis for facilitating various chemical reactions. Its unique structure, which includes a tributylstannane group and a thiophen-2-yl ring with a dioxolan-2-yl substituent, makes it particularly effective in reactions involving thiophene or dioxolane moieties. [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane's ability to act as a catalyst or reagent in these reactions is attributed to its organotin nature, which is known for its utility in organic synthesis.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane is used as a catalyst for the synthesis of various pharmaceutical compounds. [5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane's organotin nature allows it to facilitate the formation of new chemical bonds and promote the synthesis of complex molecules, which can be used as active ingredients in the development of new drugs.
Used in Chemical Research:
[5-(1,3-Dioxolan-2-yl)thiophen-2-yl]tributylstannane is also used as a research tool in the field of chemistry. Its unique structure and reactivity make it a valuable compound for studying the mechanisms of various chemical reactions, particularly those involving thiophene and dioxolane moieties. This research can contribute to the development of new synthetic methods and the discovery of novel chemical compounds with potential applications in various industries.

Upstream product

• 58268-08-9 2-(2-thienyl)-1,3-dioxolane 
• 1461-22-9 tributyltin chloride 
• 52157-62-7 2-(5-bromothiophen-2-yl)-1,3-dioxolane 

Downstream Products

• 364788-75-0 4-(2,4-dichloro-5-methoxyanilino)-7-[5-(1,3-dioxolan-2-yl)-thien-2-yl]-3-quinolinecarbonitrile 
• 700845-16-5 7-[(2,4-dichloro-5-methoxyphenyl)amino]-2-[5-(1,3-dioxolan-2-yl)thien-2-yl]thieno[3,2-b]pyridine-6-carbonitrile 
• 700845-18-7 7-[(2,4-dichloro-5-methoxyphenyl)amino]-2-(5-formylthien-2-yl)thieno[3,2-b]pyridine-6-carbonitrile 
• 1300113-91-0 5-(4-(9-butyl-9H-pyreno[4,5-d]imidazol-10-yl)phenyl)thiophene-2-carbaldehyde 
• 1394382-50-3 5-(8-(diphenylamino)-6,6,12,12-tetrakis(2-ethylhexyl)-6,12-dihydroindeno[1,2-b]fluoren-2-yl)thiophene-2-carbaldehyde 
• 1394137-50-8 C₉₄H₉₈N₂O₈S₇ 
• 1448353-09-0 7-(5-(1,3-dioxolan-2-yl)thiophen-2-yl)-9-butyl-N,N-diphenyl-9H-carbazol-2-amine 
• 1564281-84-0 4,4'-(5'-(4-(diphenylamino)phenyl)-2-thiophene-4,5-diyl)dithiophenaldehyde 

Relevant articles and documents

Bimetallic π-conjugated complexes modulated by a carbonyl spacer: Synthesis of arenetricarbonylchromium-ferrocene derivatives

Heterobimetallic complexes modulated by a carbonyl spacer have been prepared in the case of arenetricarbonylchromium and ferrocene derivatives via Claisen-Schmidt condensations.

Y-shaped metal-free D-π-(A)2 sensitizers for high-performance dye-sensitized solar cells

A series of 2,3,5-substituted thiophene-based metal-free dyes with two anchoring groups, D-π-(A)2 (DA), were synthesized for application in DSSCs. Different arylamines and 2-cyanoacrylic acid were used as the electron donor and the electron acceptor, respectively. The DSSC based on DA5 has the best power conversion efficiency (7.28%) among all devices, which is 2 times higher than that of S1 with only one anchoring group. With addition of a co-adsorbent, CDCA, the device performance of all the DA-based DSSCs are improved by 1.03 to 2-fold, with the best efficiency (7.87%) reaching 95% of that of the N719-based standard cell (8.28%). Compared with the S1 congener with only one anchor, the DA dyes can more effectively suppress charge recombination and increase electron injection efficiency, leading to higher open-circuit voltage and short-circuit current.

3-cyanoquinolines, 3-cyano-1,6-naphthyridines, and 3-cyano-1,7-naphthyridines as protein kinase inhibitors

This invention provides compounds of Formula (I), having the structure where T, Z, X, A, R1, R2a, R2b, R2c, R3, R4, and n are defined herein, or a pharmaceutically acceptable salt thereof which are useful as antineoplastic agents and in the treatment of osteoporosis and polycystic kidney disease.