350-59-4

Basic information

• Product Name: (2-chloro-1,1,2-trifluoro-ethyl)-p-tolyl ether
• CAS NO: 350-59-4
• Molecular Weight: 224.61
• Mol File: 350-59-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-chloro-1,1,2-trifluoro-ethyl)-p-tolyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (2-chloro-1,1,2-trifluoro-ethyl)-p-tolyl ether(350-59-4)
• EPA Substance Registry System: (2-chloro-1,1,2-trifluoro-ethyl)-p-tolyl ether(350-59-4)

Safety Data

• Hazardous Substances Data: 350-59-4(Hazardous Substances Data)

Upstream product

• 76-13-1 1,1,2-Trichloro-1,2,2-trifluoroethane 
• 1192-96-7 potassium p-cresolate 
• 106-44-5 p-cresol 
• 79-38-9 Chlorotrifluoroethylene 

Relevant articles and documents

Chemistry of Halogenoperfluoroalkanes> Synthesis of Fluorinated Ethers and Thioethers via Radical or Anionic Intermediates

Condensation of bromotrifluoromethane with potassium thiophenoxides in DMF is performed under pressure (2-3 atm) in a glass apparatus.Inhibition by nitrobenzene shows that a SRN1 mechanism is involved in the formation of aryl trifluoromethyl sulfides.Dichlorodifluoromethane itself reacts through a similar process to give aryl chlorodifluoromethyl sulfides.Condensation of 1,1,2-trichlorotrifluoroethane with potassium thiophenoxide or phenoxide occurs even in the presence of nitrobenzene.The formation of aryl 2,2-dichloro-1,1,2-trifluoroethyl sulfides or ethers can be explained by a chain carbanionic mechanism.