35005-74-4

Basic information

• Product Name: 4-methyl-2,3,3a,4-tetrahydro-1H-cyclopenta[b]quinoline
• CAS NO: 35005-74-4
• Molecular Formula: C₁₃H₁₅N
• Molecular Weight: 185.2649
• Mol File: 35005-74-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 315.8°C at 760 mmHg
• Flash Point: 131.8°C
• Density: 1.1g/cm³
• Vapor Pressure: 0.000426mmHg at 25°C
• Refractive Index: 1.617
• CAS DataBase Reference: 4-methyl-2,3,3a,4-tetrahydro-1H-cyclopenta[b]quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-2,3,3a,4-tetrahydro-1H-cyclopenta[b]quinoline(35005-74-4)
• EPA Substance Registry System: 4-methyl-2,3,3a,4-tetrahydro-1H-cyclopenta[b]quinoline(35005-74-4)

Safety Data

• Hazardous Substances Data: 35005-74-4(Hazardous Substances Data)

Upstream product

• 5661-06-3 2,3-dihydro-1H-cyclopenta[b]quinoline 
• 74-88-4 methyl iodide 

Relevant articles and documents

2,3;6,7-BIS(2',3'-QUINOLINO)TCU: A RIGID SYN-ORTHOCYCLOPHANE

A bis 2,3-quinoline fused derivative of tetracycloundecane is prepared by two sequential Friedlander condensations.An X-ray crystal structure indicates a dihedral angle of 50.5 deg between the two quinoline rings.

Heteroaromatic Fused Derivatives of Tetracyclo4,11.05,9>undecane

A series of rigid syn-orthocyclophanes is prepared by the Friedlaender condensation of appropriate o-aminobenzaldehyde derivatives with tetracyclo4,11.05,9>undecane-2,7-dione.The reaction may proceed in a stepwise fashion so that unsymmetrical layered compounds can be prepared.These species can be further elaborated by oxidation to quinolinequinones or N-oxides and quaternization to quinolinium salts.Molecular mechanics calculations agree closely with X-ray analysis in describing the structural properties of these cyclophanes.Analysis of the 1H-NMR and UV spectra as well as the reduction potentials of these molecules support a moderate electronic interaction between the decks.Initial investigations regarding their ability to serve as cleft-type hosts are described.