35028-02-5

Basic information

• Product Name: Ethanone, 1-[2,6-dihydroxy-4-(phenylmethoxy)phenyl]-
• Synonyms: 2,6-Dihydroxy-4-benzyloxy-resorcinol;4-benzyloxy-2,6-dihydroxyacetophenone;2.6-Dihydroxy-4-benzoyl-acetophenon
• CAS NO: 35028-02-5
• Molecular Formula: C15H14O4
• Molecular Weight: 258.274
• Mol File: 35028-02-5.mol
• Article Data: 2

Chemical Properties

• Melting Point: 188–189°C
• CAS DataBase Reference: Ethanone, 1-[2,6-dihydroxy-4-(phenylmethoxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[2,6-dihydroxy-4-(phenylmethoxy)phenyl]-(35028-02-5)
• EPA Substance Registry System: Ethanone, 1-[2,6-dihydroxy-4-(phenylmethoxy)phenyl]-(35028-02-5)

Safety Data

• Hazardous Substances Data: 35028-02-5(Hazardous Substances Data)

Usage

Preparation

Preparation from 2,4-diacetyl-5-(benzyloxy) resorcinol by selective deacetylation by refluxing in 1 N sodium hydroxide for 1 h.

Upstream product

• 65490-09-7 2'-hydroxy-4',6'-bis(methoxymethoxy)acetophenone 
• 860504-11-6 1,1'-[4-(benzyloxy)-2,6-dihydroxy-1,3-phenylene]diethanone 
• 480-66-0 2,4,6-trihydroxyacetophenone 
• 100-44-7 benzyl chloride 

Downstream Products

• 1365537-25-2 4-benzyloxy-6-hydroxy-2-(methoxymethoxy)acetophenone 
• 1365537-44-5 C₃₈H₄₆O₆Si 
• 1365537-51-4 C₃₈H₄₈O₈Si 
• 1365537-57-0 C₃₅H₃₆O₈ 
• 1365537-62-7 C₃₂H₃₀O₇ 
• 1365537-66-1 C₃₉H₃₈O₇ 
• 1365537-35-4 C₃₂H₃₀O₇ 
• 876304-97-1 apigenin-6-C-β-L-fucopyranoside 

Relevant articles and documents

The structural revision and total synthesis of carambolaflavone a

The synthesis of both enantiomers of carambolaflavone A, the antidiabetic and flavonoid C-glycoside, was achieved for the first time via a 12-longest-linear-step with 16% (l-fucose) and 11% (d-fucose) overall yields. Through the synthetic investigation, the adverse effect of 4A MS in Suzuki C-glycosylation was disclosed, the mechanism of hydrogen-bonded-phenol involved Suzuki C-glycosylation was clarified, and the authentic structure of carambolaflavone A was also determined.