35047-51-9

Basic information

• Product Name: Benzene, 5-(bromomethyl)-1,3-dimethoxy-2-methyl-
• CAS NO: 35047-51-9
• Molecular Formula: C10H13BrO2
• Molecular Weight: 245.116
• Mol File: 35047-51-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 5-(bromomethyl)-1,3-dimethoxy-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 5-(bromomethyl)-1,3-dimethoxy-2-methyl-(35047-51-9)
• EPA Substance Registry System: Benzene, 5-(bromomethyl)-1,3-dimethoxy-2-methyl-(35047-51-9)

Safety Data

• Hazardous Substances Data: 35047-51-9(Hazardous Substances Data)

Upstream product

• 61040-81-1 4-methyl-3,5-dimethoxybenzoic acid 
• 35052-27-8 3,5-dimethoxy-4-methylphenylmethyl alcohol 
• 60441-79-4 methyl 3,5-dimethoxy-4-methylbenzoate 

Downstream Products

• 187104-44-5 1,3-dimethoxy-2-methyl-5-[2-propenyl]-benzene 
• 187104-45-6 1-[3,5-dimethoxy-4-methylphenyl]-propan-2-ol 
• 187104-46-7 1,3-Dimethoxy-5-(2-methoxymethoxy-propyl)-2-methyl-benzene 
• 187104-65-0 3,7-dimethyl-8-hydroxy-6-phenylthiomethoxyisochroman 
• 187104-64-9 3,7-dimethyl-8 methoxy-6-phenylthiomethoxyisochroman 

Relevant articles and documents

Tandem Chloropalladation/Cyclization and Dearomative Cyclization toward Functionalized Tricyclic Bridged [3.2.1] Skeleton Compounds

A palladium-catalyzed tandem reaction is reported that involves chloropalladation/cyclization and dearomative cyclization to construct a tricyclic bridged [3.2.1] carbocyclic-skeleton and oxa- and aza-skeletons. In this domino process, a level of ring strain and other competitive reactions, i.e., protonolysis, β-hydride elimination, and chlorination of the C-Pd bond, were suppressed to the lowest level under mild reaction conditions.

Single step transformation of PMB ethers to bromides using a CBr4-TPP reagent system

PMB ethers are efficiently transformed to their corresponding bromides by a CBr4-TPP reagent system with a wide range of other functional groups also present in the substrate.

Syntheses of 3,7-Dimethyl-8-hydroxy-6-methoxyisochroman, the 3,7-Dimethyl-6-hydroxy-8-methoxy Isomer, and Their Ester and Ether Derivatives: Plant Growth Regulatory Activity

A systematic invesitgation of ester and ether derivatives of 3,7-dimethyl-8-hydroxy-6-methoxyisochroman and 3,7-dimethyl-6-hydroxy-8-methoxyisochroman has established that all of the derivatives synthesized exhibited activity in the wheat coleoptile assay, with several of the compounds being more active than the parent systems.