350589-51-4Relevant articles and documents
Synthesis and Utility of α-Methoxy Phosphonates with a 1,3,2-Dioxaphosphorinane Ring
Chakravarty, Manab,Srinivas,Muthiah,Kumara Swamy
, p. 2368 - 2372 (2007/10/03)
Synthesis of several α-methoxy phosphonates with the phosphorus as a part of 1,3,2-dioxaphosphorinane ring by the simple reaction of (OCH 2CMe2CH2O)PCl with acetals is described. Analogous methoxy phosphonates using (±) (C20H 12O2)PCl were also synthesized using the same route. Utility of these phosphonates in the synthesis of vinyl ethers via the Horner-Wadsworth-Emmons [HWE] reaction is demonstrated.