350831-21-9Relevant articles and documents
Nickel-catalyzed preparation of stereodefined allylic alcohols using silicon-tethered ynals
Lozanov, Mario,Montgomery, John
, p. 3259 - 3261 (2007/10/03)
The nickel-catalyzed cyclization of silicon-tethered ynals is reported. The silicon heterocycles obtained may be converted into allylic alcohols that possess a stereodefined alkene unit via a cleavage process that involves stereospecific protodesilylation of the vinyl silane functionality.