35113-75-8Relevant articles and documents
Masked acylation of m-Dinitrobenzene and deriviatives with nitroalkanes under basic conditions: Nitromethylation and α-(hydroxyimino)alkylation
Kawakami,Suzuki
, p. 1157 - 1160 (1999)
m-Dinitrobenzene and derivatives react with nitromethane or some other primary nitroalkanes in the presence of lithium tert-butoxide in 1,3- dimethyl-2-imidazolizinone (DMI) at room temperature, giving the corresponding 4-nitromethyl and 4-[1-(hydroxyimino)alkyl] derivatives, respectively, in moderate yields. These products are smoothly converted to the corresponding carbonyl compounds by oxidative Nef reaction using ozonized oxygen.
FLUORINATION OF ANIONIC ?-COMPLEXES BY CESIUM FLUOROXYSULFATE
Gakh, A. A.,Romaniko, S. V.,Ugrak, B. I.,Fainzil'berg, A. A.
, p. 1432 - 1436 (2007/10/02)
Anionic ?-complexes and related structures react with cesium fluoroxysulfate to give predominantly the C-fluoro derivatives: fluoronitrocyclohexadienes or substituted fluoronitrobenzenes.Oxidation or degradation of a complex to form substituted nitrobenzenes is also possible.The balance between all these processes is determined by the structure of the original complex.